Electrospinning of Pd-In2O3 Nanofibers for High-Performance Room Temperature Hydrogen Sensors

被引:27
作者
Chen, Chunyan [1 ]
Chen, Wanxin [1 ]
Liu, Qian [1 ]
Liu, Yuheng [1 ]
Xiao, Guoqing [1 ,2 ,3 ]
Chen, Chunlin [1 ]
Li, Fangzhou [1 ]
Zhou, Jian [4 ]
机构
[1] Southwest Petr Univ, Coll Chem & Chem Engn, Chengdu 610500, Sichuan, Peoples R China
[2] Oil & Gas Fire Protect Key Lab Sichuan Prov, Chengdu 611731, Sichuan, Peoples R China
[3] Southwest Petr Univ, State Key Lab Oil & Gas Reservoir Geol & Exploita, Chengdu 610500, Sichuan, Peoples R China
[4] Key Lab Harmful Components & Tar Reduct Cigarette, Chengdu 610100, Sichuan, Peoples R China
基金
中国国家自然科学基金;
关键词
hydrogen sensor; In(2)O(3 )nanofibers; electrospinning; Pd loading; room temperature; GAS-SENSING PROPERTIES; MESOPOROUS IN2O3; THIN-FILM; NANOPARTICLES; NO2; FABRICATION; NANORODS;
D O I
10.1021/acsanm.2c02436
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Pure In(2)O(3 )nanofibers (NFs) were first prepared by electrospinning, and then Pd-In2O3 NFs were obtained by Pd modification and further used for room temperature hydrogen (H-2) sensing. The chemical composition, morphology, and structure of the obtained samples were systematically investigated. The sensing performance of sensors was tested under different H(2 )concentrations at room temperature. The Pd@In2O3 NF sensor with a Pd loading of 1.5 wt% reflected excellent selectivity, high response (R-a/R-g = 293.6), short response time (12 s), and recovery time (23 s) for 10,000 ppm H-2 at room temperature, which is due to not only the catalytic property and chemical sensitization of Pd but also the high specific surface area from the porous structure. The outstanding sensing performance indicated that the Pd@ In2O3 nanocomposites have broad prospects for applications for detecting low concentration H2 at room temperature.
引用
收藏
页码:12646 / 12655
页数:10
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