Visible light promoted sulfonylation and sulfonylcarbonylation of alkenes

被引：9
作者：
Min, Wenjian [1 ]
Guo, Guozhe [1 ,2 ]
Yang, Caixia [1 ]
Huo, Congde [1 ]
机构：
[1] Northwest Normal Univ, Coll Chem & Chem Engn, Lanzhou 730070, Gansu, Peoples R China
[2] Longdong Univ, Coll Chem & Chem Engn, Qingyang 745000, Gansu, Peoples R China
来源：
TETRAHEDRON LETTERS | 2020年 / 61卷 / 25期
基金：
中国国家自然科学基金;
关键词：
Alkenes; TosMIC; Vinyl sulfones; beta-Keto sulfones; Visible light; Radical; P-TOLUENESULFONYLMETHYL ISOCYANIDE; BETA-KETO SULFONES; AEROBIC DIFUNCTIONALIZATION; PROPARGYLIC ALCOHOLS; TERMINAL ALKYNES; TANDEM REACTION; DUAL ROLES; CYCLIZATION; DERIVATIVES;
D O I：
10.1016/j.tetlet.2020.152029
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Visible light promoted sulfonylation and sulfonylcarbonylation reactions of readily available alkenes with TosMIC for the synthesis of valuable vinyl sulfones and beta-keto sulfones were described. A reasonable radical involved mechanism is proposed. (C) 2020 Elsevier Ltd. All rights reserved.
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页数：5
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