Visible light promoted sulfonylation and sulfonylcarbonylation of alkenes

被引：9
|
作者：
Min, Wenjian [1 ]
Guo, Guozhe [1 ,2 ]
Yang, Caixia [1 ]
Huo, Congde [1 ]
机构：
[1] Northwest Normal Univ, Coll Chem & Chem Engn, Lanzhou 730070, Gansu, Peoples R China
[2] Longdong Univ, Coll Chem & Chem Engn, Qingyang 745000, Gansu, Peoples R China
来源：
TETRAHEDRON LETTERS | 2020年 / 61卷 / 25期
基金：
中国国家自然科学基金;
关键词：
Alkenes; TosMIC; Vinyl sulfones; beta-Keto sulfones; Visible light; Radical; P-TOLUENESULFONYLMETHYL ISOCYANIDE; BETA-KETO SULFONES; AEROBIC DIFUNCTIONALIZATION; PROPARGYLIC ALCOHOLS; TERMINAL ALKYNES; TANDEM REACTION; DUAL ROLES; CYCLIZATION; DERIVATIVES;
D O I：
10.1016/j.tetlet.2020.152029
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Visible light promoted sulfonylation and sulfonylcarbonylation reactions of readily available alkenes with TosMIC for the synthesis of valuable vinyl sulfones and beta-keto sulfones were described. A reasonable radical involved mechanism is proposed. (C) 2020 Elsevier Ltd. All rights reserved.
引用
收藏
页数：5
相关论文
共 50 条
  • [1] Debenzylative Sulfonylation of Tertiary Benzylamines Promoted by Visible Light
    Fu, Ying
    Wu, Qing-Kui
    Du, Zhengyin
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2021, 2021 (12) : 1896 - 1900
  • [2] Visible Light-Promoted Isomerization of Alkenes
    Zhang, Hao
    Yu, Shouyun
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2019, 39 (01) : 95 - 108
  • [3] Visible-Light-Promoted Selenofunctionalization of Alkenes
    Conner, Elizabeth S.
    Crocker, Katherine E.
    Fernando, Ranelka G.
    Fronczek, Frank R.
    Stanley, George G.
    Ragains, Justin R.
    ORGANIC LETTERS, 2013, 15 (21) : 5558 - 5561
  • [4] Direct Sulfonylation of Alkenes with Sulfonyl Chlorides Employing Visible Light Photocatalyst
    Hosseini-Sarvari, Mona
    Keshavarz, Kimia
    CHEMISTRYSELECT, 2022, 7 (41):
  • [5] Visible light-promoted oxycarbonylation of unactivated alkenes
    Yang, Hefei
    Wang, Yuanrui
    Wang, Le-Cheng
    Wu, Xiao-Feng
    EES CATALYSIS, 2024, 2 (06): : 1247 - 1252
  • [6] Visible light promoted polyhalomethylation of alkenes: alkylation and cyclization
    Wang, Tong-Lin
    Zhang, Bo-Sheng
    Liu, Jing-Jiang
    Liu, Xiao-Jun
    Wang, Xi-Cun
    Quan, Zheng-Jun
    ORGANIC CHEMISTRY FRONTIERS, 2022, 9 (04): : 1004 - 1009
  • [7] Visible-Light-Promoted Oxo-Sulfonylation of Ynamides with Sulfonic Acids
    Wang, Lu
    Lu, Chengrong
    Yue, Yanni
    Feng, Chao
    ORGANIC LETTERS, 2019, 21 (10) : 3514 - 3517
  • [8] Visible-Light-Induced Chemoselective Synthesis of α-Chloro and Vinyl Sulfones by Sulfonylation of Alkenes
    Niu, Teng-fei
    Lin, Dan
    Xue, Lin-shuang
    Jiang, Ding-yun
    Ni, Bang-qing
    SYNLETT, 2018, 29 (03) : 364 - 368
  • [9] Visible-light-promoted phosphorylation carbonylation of unactivated alkenes
    Miao, Ren-Guan
    Wang, Yuanrui
    Wu, Xiao-Feng
    JOURNAL OF CATALYSIS, 2025, 442
  • [10] Visible-Light Promoted Distereodivergent Intramolecular Oxyamidation of Alkenes
    Ren, Xiang
    Guo, Qihang
    Chen, Jianhui
    Xie, Hujun
    Xu, Qing
    Lu, Zhan
    CHEMISTRY-A EUROPEAN JOURNAL, 2016, 22 (52) : 18695 - 18699
12345