Triple ionization of CO2 by valence and inner shell photoionization

被引：23

作者：

Eland, J. H. D. ^{[1
,2
]}

Andric, L. ^{[3
,4
,5
]}

Linusson, P. ^{[6
]}

Hedin, L. ^{[2
]}

Plogmaker, S. ^{[2
]}

Palaudoux, J. ^{[3
,4
]}

Penent, F. ^{[3
,4
]}

Lablanquie, P. ^{[3
,4
]}

Feifel, R. ^{[2
]}

机构：

[1] Univ Oxford, Dept Chem, Phys & Theoret Chem Lab, Oxford OX1 3QZ, England

[2] Uppsala Univ, Dept Phys & Astron, SE-75120 Uppsala, Sweden

[3] Univ Paris 06, UPMC, LCPMR, F-75231 Paris 05, France

[4] LCPMR UMR 7614, CNRS, F-75231 Paris 05, France

[5] Univ Paris Est, F-77454 Marne La Vallee 2, France

[6] Stockholm Univ, Dept Phys, AlbaNova Univ Ctr, SE-10691 Stockholm, Sweden

来源：

JOURNAL OF CHEMICAL PHYSICS | 2011年 / 135卷 / 13期

基金：

瑞典研究理事会;

关键词：

LL AUGER-SPECTRA; CARBON; SPECTROSCOPY; COINCIDENCE; THRESHOLD;

D O I：

10.1063/1.3643121

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Spectra of triply ionized CO2 have been obtained from photoionization of the molecule using soft x-ray synchrotron light and an efficient multi-electron coincidence technique. Although all states of the CO2+++ trication are unstable, the ionization energy for formation of molecular ions at a geometry similar to that of the neutral molecule is determined as 74 +/- 0.5 eV. (C) 2011 American Institute of Physics. [doi:10.1063/1.3643121]

引用

页数：6

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