A polyhedral oligomeric silsesquioxane functionalized copper trimesate

被引：25

作者：

Sanil, E. S. ^{[1
,2
]}

Cho, Kyung-Ho ^{[1
]}

Hong, Do-Young ^{[1
,2
]}

Lee, Ji Sun ^{[1
]}

Lee, Su-Kyung ^{[1
]}

Ryu, Sam Gon ^{[3
]}

Lee, Hae Wan ^{[3
]}

Chang, Jong-San ^{[1
]}

Hwang, Young Kyu ^{[1
,2
,4
]}

机构：

[1] Korea Res Inst Chem Technol, Catalysis Ctr Mol Engn, Taejon 305600, South Korea

[2] Univ Sci & Technol, Dept Green Chem, Taejon 305350, South Korea

[3] Agcy Def Dev, Taejon 305600, South Korea

[4] Sungkyunkwan Univ, Dept Chem, Suwon 440476, South Korea

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 40期

关键词：

METAL-ORGANIC FRAMEWORKS; CU-BTC; STABILITY; STORAGE; WATER;

D O I：

10.1039/c5cc01928a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A metal-organic framework (MOF), copper trimesate (Cu-3(BTC)(2)), was selectively functionalized with aminopropylisooctyl polyhedral oligomeric silsesquioxane (O-POSS) to make the external surface of Cu-3(BTC)(2) hydrophobic and thereby enhance the stability of the material against humidity. POSS modification was also successfully applied to other MOFs such as MOF-74 and MIL-100.

引用

页码：8418 / 8420

页数：3

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