Dinuclear zinc catalysts with unprecedented activities for the copolymerization of cyclohexene oxide and CO2

被引：132

作者：

Kissling, S. ^{[1
]}

Lehenmeier, M. W. ^{[1
]}

Altenbuchner, P. T. ^{[1
]}

Kronast, A. ^{[1
]}

Reiter, M. ^{[1
]}

Deglmann, P. ^{[2
]}

Seemann, U. B. ^{[2
]}

Rieger, B. ^{[1
]}

机构：

[1] Tech Univ Munich, WACKER Lehrstuhl Makromol Chem, D-85748 Garching, Germany

[2] BASF SE, D-67056 Ludwigshafen, Germany

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 22期

关键词：

ASYMMETRIC ALTERNATING COPOLYMERIZATION; CARBON-DIOXIDE; PROPYLENE-OXIDE; EPOXIDES; COMPLEXES; POLYMERIZATION; REACTIVITY; TERPOLYMERIZATION; POLYCARBONATES; PHENOXIDES;

D O I：

10.1039/c5cc00784d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A variety of new dinuclear zinc catalysts was developed and tested for the copolymerization of cyclohexene oxide and carbon dioxide. Electron-withdrawing groups thereby led to unprecedented activities with turnover frequencies up to 155000 h(-1). These are by far the highest polymerization rates ever reported for the copolymerization of cyclohexene oxide and CO2.

引用

页码：4579 / 4582

页数：4

共 50 条

[31] Chromium(III) amine-bis(phenolate) complexes as catalysts for copolymerization of cyclohexene oxide and CO2
Chen, Hua
Dawe, Louise N.
Kozak, Christopher M.
CATALYSIS SCIENCE & TECHNOLOGY, 2014, 4 (06) : 1547 - 1555
[32] Copolymerization of CO2 and Cyclohexene Oxide: β-Diketiminate-Supported Zn(II)OMe and Zn(II)Et Complexes as Initiators
Rajendran, N. M.
Haleel, A.
Reddy, N. Dastagiri
ORGANOMETALLICS, 2014, 33 (01) : 217 - 224
[33] Mechanistic Studies of Cyclohexene Oxide/CO2 Copolymerization by a Chromium(III) Pyridylamine-Bis(Phenolate) Complex
Devaine-Pressing, Katalin
Kozak, Christopher M.
CHEMSUSCHEM, 2017, 10 (06) : 1266 - 1273
[34] Copolymerization of cyclohexene oxide with CO2 catalyzed by tridentate N-heterocyclic carbene titanium(IV) complexes
Quadri, Coralie C.
Le Roux, Erwan
DALTON TRANSACTIONS, 2014, 43 (11) : 4242 - 4246
[35] Scalable Bifunctional Organoboron Catalysts for Copolymerization of CO2 and Epoxides with Unprecedented Efficiency
Yang, Guan-Wen
Zhang, Yao-Yao
Xie, Rui
Wu, Guang-Peng
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2020, 142 (28) : 12245 - 12255
[36] Highly Active, Bifunctional Co(III)-Salen Catalyst for Alternating Copolymerization of CO2 with Cyclohexene Oxide and Terpolymerization with Aliphatic Epoxides
Ren, Wei-Min
Zhang, Xiao
Liu, Ye
Li, Jian-Feng
Wang, Hui
Lu, Xiao-Bing
MACROMOLECULES, 2010, 43 (03) : 1396 - 1402
[37] Mechanism and Design Principles for Controlling Stereoselectivity in the Copolymerization of CO2/Cyclohexene Oxide by Indium(III) Phosphasalen Catalysts
Reddi, Yernaidu
Cramer, Christopher J.
ACS CATALYSIS, 2021, 11 (24) : 15244 - 15251
[38] Synthesis of Chiral C2-Symmetric Bimetallic Zinc Complexes of Amido-Oxazolinates and Their Application in Copolymerization of CO2 and Cyclohexene Oxide
Abbina, Srinivas
Chidara, Vamshi K.
Bian, Shi
Ugrinov, Angel
Du, Guodong
CHEMISTRYSELECT, 2016, 1 (12): : 3175 - 3183
[39] Copolymerization of CO2 and Cyclohexene Oxide Mediated by Yb(salen)-Based Complexes
Decortes, Antonello
Haak, Robert M.
Martin, Carmen
Martinez Belmonte, Marta
Martin, Eddy
Benet-Buchholz, Jordi
Kleij, Arjan W.
MACROMOLECULES, 2015, 48 (22) : 8197 - 8207
[40] Di-magnesium and zinc catalysts for the copolymerization of phthalic anhydride and cyclohexene oxide
Saini, Prabhjot K.
Romain, Charles
Zhu, Yunqing
Williams, Charlotte K.
POLYMER CHEMISTRY, 2014, 5 (20) : 6068 - 6075

← 1 2 3 4 5 →