Dinuclear zinc catalysts with unprecedented activities for the copolymerization of cyclohexene oxide and CO2

被引：132
|
作者：
Kissling, S. [1 ]
Lehenmeier, M. W. [1 ]
Altenbuchner, P. T. [1 ]
Kronast, A. [1 ]
Reiter, M. [1 ]
Deglmann, P. [2 ]
Seemann, U. B. [2 ]
Rieger, B. [1 ]
机构：
[1] Tech Univ Munich, WACKER Lehrstuhl Makromol Chem, D-85748 Garching, Germany
[2] BASF SE, D-67056 Ludwigshafen, Germany
来源：
CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 22期
关键词：
ASYMMETRIC ALTERNATING COPOLYMERIZATION; CARBON-DIOXIDE; PROPYLENE-OXIDE; EPOXIDES; COMPLEXES; POLYMERIZATION; REACTIVITY; TERPOLYMERIZATION; POLYCARBONATES; PHENOXIDES;
D O I：
10.1039/c5cc00784d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A variety of new dinuclear zinc catalysts was developed and tested for the copolymerization of cyclohexene oxide and carbon dioxide. Electron-withdrawing groups thereby led to unprecedented activities with turnover frequencies up to 155000 h(-1). These are by far the highest polymerization rates ever reported for the copolymerization of cyclohexene oxide and CO2.
引用
收藏
页码：4579 / 4582
页数：4
相关论文
共 50 条
  • [1] Copolymerization of cyclohexene oxide with CO2 by using intramolecular dinuclear zinc catalysts
    Xiao, YL
    Wang, Z
    Ding, KL
    CHEMISTRY-A EUROPEAN JOURNAL, 2005, 11 (12) : 3668 - 3678
  • [2] (Pyrazolylethyl-amine)zinc(II) carboxylate complexes as catalysts for the copolymerization of CO2 and cyclohexene oxide
    Matiwane, Anelisa
    Obuah, Collins
    Darkwa, James
    POLYHEDRON, 2020, 190 (190)
  • [3] Alternating Copolymerization of CO2 and Cyclohexene Oxide by New Pyridylamidozinc(II) Catalysts
    D'Auria, Ilaria
    D'Alterio, Massimo Christian
    Talarico, Giovanni
    Pellecchia, Claudio
    MACROMOLECULES, 2018, 51 (23) : 9871 - 9877
  • [4] Di- and Tri-Zinc Catalysts for the Low-Pressure Copolymerization of CO2 and Cyclohexene Oxide
    Kember, Michael R.
    White, Andrew J. P.
    Williams, Charlotte K.
    INORGANIC CHEMISTRY, 2009, 48 (19) : 9535 - 9542
  • [5] Flexibly Tethered Dinuclear Zinc Complexes: A Solution to the Entropy Problem in CO2/Epoxide Copolymerization Catalysis?
    Lehenmeier, Maximilian W.
    Kissling, Stefan
    Altenbuchner, Peter T.
    Bruckmeier, Christian
    Deglmann, Peter
    Brym, Anna-Katharina
    Rieger, Bernhard
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (37) : 9821 - 9826
  • [6] Cooperative rare earth metal-zinc based heterometallic catalysts for copolymerization of CO2 and cyclohexene oxide
    Qin, Jie
    Xu, Bin
    Zhang, Yong
    Yuan, Dan
    Yao, Yingming
    GREEN CHEMISTRY, 2016, 18 (15) : 4270 - 4275
  • [7] Aluminum bisphenoxides:: Promising challengers for a catalyzed copolymerization of cyclohexene oxide with CO2
    Zevaco, Thomas A.
    Sypien, Jakub
    Janssen, Annette
    Walter, Olaf
    Dinjus, Eckhard
    CATALYSIS TODAY, 2006, 115 (1-4) : 151 - 161
  • [8] Copolymerization of propylene oxide and CO2 catalyzed by dinuclear salcy?CoCl complex
    Huang, Jie
    Xu, Yunpeng
    Wang, Meige
    Duan, Zhongyu
    JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY, 2020, 57 (02): : 131 - 138
  • [9] Modeling the Mechanism of CO2/Cyclohexene Oxide Copolymerization Catalyzed by Chiral Zinc β-Diiminates: Factors Affecting Reactivity and Isotacticity
    Shao, Huiling
    Reddi, Yernaidu
    Cramer, Christopher J.
    ACS CATALYSIS, 2020, 10 (15): : 8870 - 8879
  • [10] A novel zinc diimide catalyst for copolymerization of CO2 and cyclohexene oxide
    Min Z.
    Liban C.
    Baohuau L.
    Zhairong Y.
    Gang Q.
    Zhoumei L.
    Polymer Bulletin, 2001, 47 (3) : 255 - 260
12345