Dinuclear zinc catalysts with unprecedented activities for the copolymerization of cyclohexene oxide and CO2

被引：133
|
作者：
Kissling, S. [1 ]
Lehenmeier, M. W. [1 ]
Altenbuchner, P. T. [1 ]
Kronast, A. [1 ]
Reiter, M. [1 ]
Deglmann, P. [2 ]
Seemann, U. B. [2 ]
Rieger, B. [1 ]
机构：
[1] Tech Univ Munich, WACKER Lehrstuhl Makromol Chem, D-85748 Garching, Germany
[2] BASF SE, D-67056 Ludwigshafen, Germany
来源：
CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 22期
关键词：
ASYMMETRIC ALTERNATING COPOLYMERIZATION; CARBON-DIOXIDE; PROPYLENE-OXIDE; EPOXIDES; COMPLEXES; POLYMERIZATION; REACTIVITY; TERPOLYMERIZATION; POLYCARBONATES; PHENOXIDES;
D O I：
10.1039/c5cc00784d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A variety of new dinuclear zinc catalysts was developed and tested for the copolymerization of cyclohexene oxide and carbon dioxide. Electron-withdrawing groups thereby led to unprecedented activities with turnover frequencies up to 155000 h(-1). These are by far the highest polymerization rates ever reported for the copolymerization of cyclohexene oxide and CO2.
引用
收藏
页码：4579 / 4582
页数：4
相关论文
共 50 条
  • [1] Dinuclear catalysts for the copolymerization of cyclohexene oxide and CO2
    Kember, Michael R.
    Jutz, Fabian
    White, Andrew J.
    Buchard, Antoine
    Williams, Charlotte K.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2011, 242
  • [2] Copolymerization of cyclohexene oxide with CO2 by using intramolecular dinuclear zinc catalysts
    Xiao, YL
    Wang, Z
    Ding, KL
    CHEMISTRY-A EUROPEAN JOURNAL, 2005, 11 (12) : 3668 - 3678
  • [3] Dinuclear zinc catalysts for the copolymerization of CO2 and epoxides
    Lehenmeier, Maximilian W.
    Bruckmeier, Christian
    Deglmann, Peter
    Ott, Anna-Katharina
    Rieger, Bernhard
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2010, 240
  • [4] Copolymerization of CO2 and cyclohexene oxide
    Super, M
    Beckman, EJ
    MACROMOLECULAR SYMPOSIA, 1998, 127 : 89 - 108
  • [5] A novel zinc diimide catalyst for copolymerization Of CO2 and cyclohexene oxide
    Zhang, M
    Chen, LB
    Liu, BH
    Yan, ZR
    Qin, G
    Li, ZM
    POLYMER BULLETIN, 2001, 47 (3-4) : 255 - 260
  • [6] A novel zinc diimide catalyst for copolymerization of CO2 and cyclohexene oxide
    Min Z.
    Liban C.
    Baohuau L.
    Zhairong Y.
    Gang Q.
    Zhoumei L.
    Polymer Bulletin, 2001, 47 (3) : 255 - 260
  • [7] (Pyrazolylethyl-amine)zinc(II) carboxylate complexes as catalysts for the copolymerization of CO2 and cyclohexene oxide
    Matiwane, Anelisa
    Obuah, Collins
    Darkwa, James
    POLYHEDRON, 2020, 190 (190)
  • [8] Alternating Copolymerization of CO2 and Cyclohexene Oxide by New Pyridylamidozinc(II) Catalysts
    D'Auria, Ilaria
    D'Alterio, Massimo Christian
    Talarico, Giovanni
    Pellecchia, Claudio
    MACROMOLECULES, 2018, 51 (23) : 9871 - 9877
  • [9] Asymmetric alternating copolymerization of cyclohexene oxide and CO2 with dimeric zinc complexes
    Nozaki, K. (nozaki@chembio.t.u-tokyo.ac.jp), 1600, American Chemical Society (125):
  • [10] Asymmetric alternating copolymerization of cyclohexene oxide and CO2 with dimeric zinc complexes
    Nakano, K
    Nozaki, K
    Hiyama, T
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (18) : 5501 - 5510
12345