Sequential sputtering/selenization technique for the growth of CuInSe2 thin films

被引:25
作者
Nakada, T [1 ]
Kunioka, A [1 ]
机构
[1] Aoyama Gakuin Univ, Dept Elect Engn & Elect, Setagaya Ku, Tokyo 157, Japan
来源
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS | 1998年 / 37卷 / 9AB期
关键词
CuInSe2; sequential sputter/selenization; sputtering; selenization; thin films; solar cells;
D O I
10.1143/JJAP.37.L1065
中图分类号
O59 [应用物理学];
学科分类号
摘要
We have proposed a sequential sputtering/selenization technique and apparatus for the growth of CuInSe2 (CIS)-based thin films. The apparatus consists of a cylindrical rotating drum for holding substrates and three horizontally interconnected subchambers for Cu, In, and Se fluxes. The serious problem associated with hybrid sputtering of. metal target contamination by Se flux has been greatly reduced by the current geometric design. In this method, a very thin Cu/In stacked layer is first sputter-deposited, and then selenized with thermally evaporated Se vapor at each rotation of the drum. Polycrystalline CIS films for solar cells were grown by sequentially repeating these steps, which prevented the formation of the micron-sized voids usually observed in CIS-based thin films grown by selenization.
引用
收藏
页码:L1065 / L1067
页数:3
相关论文
共 10 条
[1]  
ARYA RR, 1991, P 22 IEEE PHOT SPEC, P903
[2]  
Basol B. M., 1996, AIP C P, V394
[3]  
Dimmler B., 1996, P 25 IEEE PHOT SPEC, P757
[4]  
KUSHIYA K, 1996, 9 PHOT SCI ENG C MIY, P149
[5]   MICROSTRUCTURAL CHARACTERIZATION FOR SPUTTER-DEPOSITED CUINSE2 FILMS AND PHOTOVOLTAIC DEVICES [J].
NAKADA, T ;
MIGITA, K ;
NIKI, S ;
KUNIOKA, A .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1995, 34 (9A) :4715-4721
[6]   POLYCRYSTALLINE CUINSE2 THIN-FILMS FOR SOLAR-CELLS BY 3-SOURCE MAGNETRON SPUTTERING [J].
NAKADA, T ;
MIGITA, K ;
KUNIOKA, A .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS & EXPRESS LETTERS, 1993, 32 (8B) :L1169-L1172
[7]  
NAKADA T, 1998, P 2 WORLD C EXH PHOT
[8]  
NAKADA T, 1987, PHOT SCI ENG C TOK 1, P553
[9]   Real time composition monitoring methods in physical vapor deposition of Cu(In,Ga)Se-2 thin films [J].
Negami, T ;
Nishitani, M ;
Kohara, N ;
Hashimoto, Y ;
Wada, T .
THIN FILMS FOR PHOTOVOLTAIC AND RELATED DEVICE APPLICATIONS, 1996, 426 :267-278
[10]   The performance of Cu(In,Ga)Se-2-based solar cells in conventional and concentrator applications [J].
Tuttle, JR ;
Ward, JS ;
Duda, A ;
Berens, TA ;
Contreras, MA ;
Ramanathan, KR ;
Tennant, AL ;
Keane, J ;
Cole, ED ;
Emery, K ;
Noufi, R .
THIN FILMS FOR PHOTOVOLTAIC AND RELATED DEVICE APPLICATIONS, 1996, 426 :143-151