Luminescent complexes made from chelating isocyanide ligands and earth-abundant metals

被引：27

作者：

Bueldt, Laura A. ^{[1
,2
]}

Wenger, Oliver S. ^{[1
]}

机构：

[1] Univ Basel, Dept Chem, St Johanns Ring 19, CH-4056 Basel, Switzerland

[2] Univ Tubingen, Inst Inorgan Chem, Morgenstelle 18, D-72076 Tubingen, Germany

来源：

DALTON TRANSACTIONS | 2017年 / 46卷 / 44期

基金：

瑞士国家科学基金会;

关键词：

HETEROCYCLIC CARBENE COMPLEXES; LIGHT PHOTOREDOX CATALYSIS; TRANSFER RADICAL-ADDITION; EXCITED-STATE LIFETIMES; PHOTOSENSITIZERS; PHOTOCHEMISTRY; MOLYBDENUM(0); TUNGSTEN(0); ANALOG; IRON;

D O I：

10.1039/c7dt03620e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In this invited frontier article, recently discovered d(6) and d(10) complexes with long-lived metal-to-ligand charge transfer (MLCT) excited states are highlighted. Chelating diisocyanide ligands give access to emissive Mo(0) and Cr(0) complexes with d(6) electron configuration exhibiting photophysical properties similar to those of Ru(II) polypyridines or cyclometalated Ir(III) complexes. With Ni(0), these ligands yield luminescent tetrahedral d(10) complexes similar to isoelectronic Cu(I) bis(diimine) compounds.

引用

页码：15175 / 15177

页数：3

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