Ultrafast Intermolecular Energy Transfer from Vibrations to Electronic Motion

被引:15
作者
Cederbaum, Lorenz S. [1 ]
机构
[1] Heidelberg Univ, Theoret Chem, Phys Chem Inst, Neuenheimer Feld 229, D-69120 Heidelberg, Germany
基金
欧洲研究理事会;
关键词
INTERATOMIC COULOMBIC DECAY; NEGATIVE-ION; EXCITATION-ENERGY; CROSS-SECTION; PHOTODETACHMENT; SPECTROSCOPY; DYNAMICS; AFFINITIES; CHEMISTRY; STATES;
D O I
10.1103/PhysRevLett.121.223001
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
It is discussed how vibrationally excited molecules in their electronic ground state can transfer their vibrational energy to the electronic motion of neighbors and ionize them. Based on explicit examples of vibrationally excited molecules and anionic neighbors, it is demonstrated that the transfer can be extremely efficient at intermolecular distances much beyond distances at which the molecule and its neighbor can form a bond.
引用
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页数:6
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