Ultrafast Intermolecular Energy Transfer from Vibrations to Electronic Motion

被引：15

作者：

Cederbaum, Lorenz S. ^{[1
]}

机构：

[1] Heidelberg Univ, Theoret Chem, Phys Chem Inst, Neuenheimer Feld 229, D-69120 Heidelberg, Germany

来源：

PHYSICAL REVIEW LETTERS | 2018年 / 121卷 / 22期

基金：

欧洲研究理事会;

关键词：

INTERATOMIC COULOMBIC DECAY; NEGATIVE-ION; EXCITATION-ENERGY; CROSS-SECTION; PHOTODETACHMENT; SPECTROSCOPY; DYNAMICS; AFFINITIES; CHEMISTRY; STATES;

D O I：

10.1103/PhysRevLett.121.223001

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

It is discussed how vibrationally excited molecules in their electronic ground state can transfer their vibrational energy to the electronic motion of neighbors and ionize them. Based on explicit examples of vibrationally excited molecules and anionic neighbors, it is demonstrated that the transfer can be extremely efficient at intermolecular distances much beyond distances at which the molecule and its neighbor can form a bond.

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页数：6

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共 65 条

[1] MEASUREMENT OF THE INFRARED PHOTODETACHMENT CROSS-SECTION OF NO- [J].

ALZAAL, M ;

MILLER, HC ;

FARLEY, JW .

PHYSICAL REVIEW A, 1986, 33 (02) :977-985

[2] Atomic negative ions: structure, dynamics and collisions [J].

Andersen, T .

PHYSICS REPORTS-REVIEW SECTION OF PHYSICS LETTERS, 2004, 394 (4-5) :157-313

[3] VIBRATION-ROTATIONAL EINSTEIN COEFFICIENTS FOR HF DF AND HCI DCI [J].

ARUNAN, E ;

SETSER, DW ;

OGILVIE, JF .

JOURNAL OF CHEMICAL PHYSICS, 1992, 97 (03) :1734-1741

[4] Mechanism of interatomic Coulombic decay in clusters -: art. no. 263002 [J].

Averbukh, V ;

Müller, IB ;

Cederbaum, LS .

PHYSICAL REVIEW LETTERS, 2004, 93 (26)

[5] Interatomic electronic decay processes in singly and multiply ionized clusters [J].

Averbukh, V. ;

Demekhin, Ph. V. ;

Kolorenc, P. ;

Scheit, S. ;

Stoychev, S. D. ;

Kuleff, A. I. ;

Chiang, Y. -C. ;

Gokhberg, K. ;

Kopelke, S. ;

Sisourat, N. ;

Cederbaum, L. S. .

JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 2011, 183 (1-3) :36-47

[6] Dynamics of interatomic Coulombic decay in quantum dots [J].

Bande, Annika ;

Gokhberg, Kirill ;

Cederbaum, Lorenz S. .

JOURNAL OF CHEMICAL PHYSICS, 2011, 135 (14)

[7] The electron as a protecting group. 3. Generation of acenaphthyne radical anion and the determination of the heat of formation of a strained cycloalkyne [J].

Broadus, KM ;

Kass, SR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (18) :4189-4196

[8] HIGH-RESOLUTION ROTATIONAL SPECTRUM, DUNHAM COEFFICIENTS, AND POTENTIAL ENERGY FUNCTION OF NaCl [J].

Cabezas, C. ;

Cernicharo, J. ;

Quintana-Lacaci, G. ;

Pena, I. ;

Agundez, M. ;

Prieto, L. Velilla ;

Castro-Carrizo, A. ;

Zuniga, J. ;

Bastida, A. ;

Alonso, J. L. ;

Requena, A. .

ASTROPHYSICAL JOURNAL, 2016, 825 (02)

[9] Efficient non-resonant intermolecular vibrational energy transfer [J].

Cederbaum, Lorenz S. .

MOLECULAR PHYSICS, 2019, 117 (15-16) :1950-1955

[10] Giant intermolecular decay and fragmentation of clusters [J].

Cederbaum, LS ;

Zobeley, J ;

Tarantelli, F .

PHYSICAL REVIEW LETTERS, 1997, 79 (24) :4778-4781

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