Thiadiazole containing N- and S-rich highly ordered periodic mesoporous organosilica for efficient removal of Hg(ii) from polluted water

被引:49
作者
Das, Surajit [1 ]
Chatterjee, Sauvik [1 ]
Mondal, Saptarsi [2 ,3 ]
Modak, Arindam [4 ]
Chandra, Bijan Krishna [1 ,5 ]
Das, Suparna [6 ,7 ]
Nessim, Gilbert Daniel [6 ,7 ]
Majee, Adinath [4 ]
Bhaumik, Asim [1 ]
机构
[1] Indian Assoc Cultivat Sci, Sch Mat Sci, Kolkata 700032, India
[2] Inst for Basic Sci Korea, Ctr Mol Spect & Dynam, Seoul 02841, South Korea
[3] Korea Univ, Dept Chem, Seoul 02841, South Korea
[4] Ariel Univ, Dept Chem Sci, IL-40700 Ariel, Israel
[5] Visva Bharati Univ, Dept Chem, Santini Ketan 731235, India
[6] Bar Ilan Univ, Dept Chem, IL-5290002 Ramat Gan, Israel
[7] Bar Ilan Univ, Bar Ilan Inst Technol & Adv Mat BINA, IL-5290002 Ramat Gan, Israel
关键词
COVALENT ORGANIC FRAMEWORKS; MERCURY; SILICA; ADSORPTION; ADSORBENT; CAPTURE; SULFUR; WASTE; HG2+;
D O I
10.1039/d0cc00407c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new N- and S-rich highly ordered periodic mesoporous organosilica material DMTZ-PMO bearing thiadiazole and thiol moieties inside the pore-wall of a 2D-hexagonal nanomaterial has been synthesized. DMTZ-PMO shows a very high surface area (971 m(2) g(-1)), and can be used for efficient and fast removal of Hg2+ from polluted water with a very high Hg2+ uptake capacity of 2081 mg g(-1).
引用
收藏
页码:3963 / 3966
页数:4
相关论文
共 45 条
[1]   High performance methyl orange capture on magnetic nanoporous MCM-41 prepared by incipient wetness impregnation method [J].
Albayati, Talib Mohammed ;
Alwan, Ghanim Magbol ;
Mahdy, Omar Sabah .
KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2017, 34 (01) :259-265
[2]   Benzoylthiourea-modified mesoporous silica for mercury(II) removal [J].
Antochshuk, V ;
Olkhovyk, O ;
Jaroniec, M ;
Park, IS ;
Ryoo, R .
LANGMUIR, 2003, 19 (07) :3031-3034
[3]   1-allyl-3-propylthiourea modified mesoporous silica for mercury removal [J].
Antochshuk, V ;
Jaroniec, M .
CHEMICAL COMMUNICATIONS, 2002, (03) :258-259
[4]   Heavy metal adsorption by functionalized clays [J].
Celis, R ;
Hermosín, MC ;
Cornejo, J .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2000, 34 (21) :4593-4599
[5]   Highly luminescent organic-inorganic hybrid mesoporous silicas containing tunable chemosensor inside the pore wall [J].
Chandra, Debraj ;
Yokoi, Toshiyuki ;
Tatsumi, Takashi ;
Bhaumik, Asim .
CHEMISTRY OF MATERIALS, 2007, 19 (22) :5347-5354
[6]   Three-dimensional cubic (Im3m) periodic mesoporous organosilicas with benzene- and thiophene-bridging groups [J].
Cho, Eun-Bum ;
Kim, Dukjoon ;
Gorka, Joanna ;
Jaroniec, Mietek .
JOURNAL OF MATERIALS CHEMISTRY, 2009, 19 (14) :2076-2081
[7]   MERCURY - MAJOR ISSUES IN ENVIRONMENTAL-HEALTH [J].
CLARKSON, TW .
ENVIRONMENTAL HEALTH PERSPECTIVES, 1993, 100 :31-38
[8]   Thiol-Functionalized Zr-Based Metal-Organic Framework for Capture of Hg(II) through a Proton Exchange Reaction [J].
Ding, Lin ;
Luo, Xubiao ;
Shao, Penghui ;
Yang, Jiakuan ;
Sung, Dongqi .
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2018, 6 (07) :8494-8502
[9]   Phthalocyanine-based mesoporous organosilica nanoparticles: NIR photodynamic efficiency and siRNA photochemical internalization [J].
Ekineker, Guelcin ;
Nguyen, Christophe ;
Bayir, Suemeyra ;
Dominguez Gil, Sofia ;
Isci, Umit ;
Daurat, Morgane ;
Godefroy, Anastasia ;
Raehm, Laurence ;
Charnay, Clarence ;
Oliviero, Erwan ;
Ahsen, Vefa ;
Gary-Bobo, Magali ;
Durand, Jean-Olivier ;
Dumoulin, Fabienne .
CHEMICAL COMMUNICATIONS, 2019, 55 (77) :11619-11622
[10]   Historical atmospheric pollution trends in Southeast Asia inferred from lake sediment records [J].
Engels, S. ;
Fong, L. S. R. Z. ;
Chen, Q. ;
Leng, M. J. ;
McGowan, S. ;
Idris, M. ;
Rose, N. L. ;
Ruslan, M. S. ;
Taylor, D. ;
Yang, H. .
ENVIRONMENTAL POLLUTION, 2018, 235 :907-917