High nonlinear optical response in 4-chlorothiazole-based azo dyes

被引:48
作者
Borbone, Fabio [1 ]
Carella, Antonio [1 ]
Ricciotti, Laura [1 ]
Tuzi, Angela [1 ]
Roviello, Antonio [1 ]
Barsella, Alberto [2 ]
机构
[1] Univ Naples Federico II, Dipartimento Chim Paolo Corradini, I-80126 Naples, Italy
[2] GONLO, CNRS, IPCMS, F-67037 Strasbourg, France
关键词
NLO chromophore; Azo dye; Donor/acceptor; Chlorothiazole; Bathochromism; PUSH-PULL CHROMOPHORES; SOL-GEL MATERIALS; POLYMERIC MATERIALS; DESIGN; BANDS;
D O I
10.1016/j.dyepig.2010.07.011
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Four azo dyes showing high nonlinear optical properties were prepared based on a 4-chlorothiazole azo moiety functionalized with strong acceptor groups and/or further donor/acceptor groups along the conjugated backbone The effects of the acceptors as well as the lateral donor/acceptor groups upon absorption properties thermal stability and second order nonlinear optical activity were evaluated (C) 2010 Elsevier Ltd All rights reserved
引用
收藏
页码:290 / 295
页数:6
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