Design Criteria for High-Temperature Single-Molecule Magnets

被引：212

作者：

Chilton, Nicholas F. ^{[1
]}

机构：

[1] Univ Manchester, Sch Chem, Manchester M13 9PL, Lancs, England

来源：

INORGANIC CHEMISTRY | 2015年 / 54卷 / 05期

关键词：

ION MAGNET; BLOCKING; COMPLEX; RELAXATION; ANISOTROPY; SYMMETRY;

D O I：

10.1021/acs.inorgchem.5b00089

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Design criteria to obtain slow magnetic relaxation are theoretically investigated for two-coordinate complexes of Dy-III. It is shown that large energy barriers to magnetic relaxation, U-eff, can ,be achieved in the absence of near-linearity and generally that any two-coordinate complex of Dy-III is an attractive synthetic target that may possess U-eff > 1000 cm(-1). These large U-eff values are immediately diminished if axial ligation is disrupted by solvent coordination.

引用

页码：2097 / 2099

页数：3

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