Preparation and characterization of trimethylsilyl-substituted benzimidazole metal complexes and structural characterization of dichlorobis[1-(trimethylsilyl)methyl-1H-benzimidazole-N3]cobalt(II)

被引：15

作者：

Sireci, Nihat ^{[2
]}

Kucukbay, Hasan ^{[1
]}

Akkurt, Mehmet ^{[3
]}

Yalcin, Serife Pinar ^{[4
]}

Tahir, M. Nawaz ^{[5
]}

Ott, Holger ^{[6
]}

机构：

[1] Inonu Univ, Dept Chem, Fac Arts & Sci, TR-44280 Malatya, Turkey

[2] Adiyaman Univ, Dept Chem, Fac Arts & Sci, TR-02040 Adiyaman, Turkey

[3] Erciyes Univ, Dept Phys, Fac Arts & Sci, TR-38039 Kayseri, Turkey

[4] Harran Univ, Dept Phys, Fac Arts & Sci, TR-63300 Sanliurfa, Turkey

[5] Univ Sargodha, Dept Phys, Sargodha, Pakistan

[6] Bruker AXS GmbH, D-76187 Karlsruhe, Germany

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2010年 / 63卷 / 18期

关键词：

Benzimidazole metal complexes; Silyl-substituted benzimidazoles; Crystal structure; ANTIMICROBIAL ACTIVITY; CARBENE COMPLEXES; CRYSTAL-STRUCTURE; SOLVATE;

D O I：

10.1080/00958972.2010.509432

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The ligands 1-trimethylsilylmethylbenzimidazole, 5-methyl-1-trimethylsilylmethylbenzimidazole, and 5-nitro-1-trimethylsilylmethylbenzimidazole and their Co(II) and Zn(II) complexes were synthesized and characterized by 1H-NMR, 13C-NMR, and elemental analyses. The crystal structure of dichlorobis[1-(trimethylsilyl)methyl-1H-benzimidazole-N3]cobalt(II) has been determined by single crystal X-ray diffraction.

引用

页码：3218 / 3228

页数：11

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