Fabrication, Characterization and Photocatalytic Activity of Copper Oxide Nanowires Formed by Anodization of Copper Foams

被引:21
作者
Abd-Elnaiem, Alaa M. [1 ,2 ]
Abdel-Rahim, Moustafa A. [1 ,2 ]
Abdel-Latief, Atta Y. [1 ,2 ]
Mohamed, Ahmed Abdel-Rahim [1 ,2 ]
Mojsilovic, Kristina [3 ]
Stepniowski, Wojciech Jerzy [4 ]
机构
[1] Assiut Univ, Fac Sci, Phys Dept, Assiut 71516, Egypt
[2] Arab Republ Egypt, Acad Sci Res & Technol ASRT, Cairo 11516, Egypt
[3] Univ Belgrade, Fac Phys, Studentski Trg 12-16, Belgrade 11000, Serbia
[4] Mil Univ Technol, Fac Adv Technol & Chem, Inst Mat Sci & Engn, Kaliskiego 2 Str, PL-00908 Warsaw, Poland
关键词
copper oxides; anodization; nanowires; FTIR; photocatalytic decolorization; nanostructures; tenorite; cuprite; paramelconite; malachite; TIO2; PHOTOCATALYSIS; CUO; OXIDATION; FILMS; NANONEEDLE; MECHANISM; EFFICIENT; KINETICS; ARRAYS; CARBON;
D O I
10.3390/ma14175030
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In recent paper anodization of copper foams in 0.1 M K2CO3 is reported. Anodization was performed in the voltage range of 5-25 V and in all the cases oxides with a developed surface area were obtained. However, anodizing only at 20 and 25 V resulted in the formation of nanostruc-tures. In all the cases, the products of anodizing consisted of crystalline phases like cuprite (Cu2O), tenorite (CuO), parameconite (Cu4O3) as well as spertiniite (Cu(OH)(2)). Copper foams after ano-dizing were applied as catalysts in the photocatalytic decolorization of a model organic compound such as methylene blue. The highest photocatalytic activity was observed for samples anodized at 25 V and closely followed by samples anodized at 5 V. The anodized copper foams proved to be a useful material in enhancing the photocatalytic efficiency of organic dye decomposition.
引用
收藏
页数:13
相关论文
共 36 条
[1]   Using cocoa (Theobroma cacao) shell-based activated carbon to remove 4-nitrophenol from aqueous solution: Kinetics and equilibrium studies [J].
Ahmad, Fisal ;
Daud, Wan Mohd Ashri Wan ;
Ahmad, Mohd Azmier ;
Radzi, Rosinah .
CHEMICAL ENGINEERING JOURNAL, 2011, 178 :461-467
[2]   Pushing the Limits of Rapid Anodic Growth of CuO/Cu(OH)2 Nanoneedles on Cu for the Methanol Oxidation Reaction: Anodization pH Is the Game Changer [J].
Anantharaj, Sengeni ;
Sugime, Hisashi ;
Yamaoka, Shohei ;
Noda, Suguru .
ACS APPLIED ENERGY MATERIALS, 2021, 4 (01) :899-912
[3]   Ultrafast Growth of a Cu(OH)2-CuO Nanoneedle Array on Cu Foil for Methanol Oxidation Electrocatalysis [J].
Anantharaj, Sengeni ;
Sugime, Hisashi ;
Noda, Suguru .
ACS APPLIED MATERIALS & INTERFACES, 2020, 12 (24) :27327-27338
[4]   Optical, structural and phase transition properties of Cu2O, CuO and Cu2O/CuO: Their photoelectrochemical sensor applications [J].
Balik, Meral ;
Bulut, Veysel ;
Erdogan, Ibrahim Y. .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2019, 44 (34) :18744-18755
[5]   Effect of processing parameters on pore structure and thickness of anodic aluminum oxide (AAO) tubular membranes [J].
Belwalkar, A. ;
Grasing, E. ;
Van Geertruyden, W. ;
Huang, Z. ;
Misiolek, W. Z. .
JOURNAL OF MEMBRANE SCIENCE, 2008, 319 (1-2) :192-198
[6]   A Facile Synthesis of Cu2O and CuO Nanoparticles Via Sonochemical Assisted Method [J].
Botsa, Sathish Mohan ;
Dharmasoth, Ramadevi ;
Basavaiah, Keloth .
CURRENT NANOSCIENCE, 2019, 15 (02) :209-213
[7]   Biofabrication of highly pure copper oxide nanoparticles using wheat seed extract and their catalytic activity: A mechanistic approach [J].
Buazar, Foad ;
Sweidi, Sajjad ;
Badri, Mohammad ;
Kroushawi, Feisal .
GREEN PROCESSING AND SYNTHESIS, 2019, 8 (01) :691-702
[8]   Role of CuO in the modification of the photocatalytic water splitting behavior of TiO2 nanotube thin films [J].
de Brito, Juliana Ferreira ;
Tavella, Francesco ;
Genovese, Chiara ;
Ampelli, Claudio ;
Boldrin Zanoni, Maria Valnice ;
Centi, Gabriele ;
Perathoner, Siglinda .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2018, 224 :136-145
[9]   An efficient and low-cost photoanode for backside illuminated dye-sensitized solar cell using 3D porous alumina [J].
El-Said, Waleed A. ;
Abdel-Shakour, M. ;
Abd-Elnaiem, Alaa M. .
MATERIALS LETTERS, 2018, 222 :126-130
[10]   Copper oxide nanowires: a review of growth [J].
Filipic, G. ;
Cvelbar, U. .
NANOTECHNOLOGY, 2012, 23 (19)