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Fabrication, Characterization and Photocatalytic Activity of Copper Oxide Nanowires Formed by Anodization of Copper Foams
被引:21
作者:
Abd-Elnaiem, Alaa M.
[1
,2
]
Abdel-Rahim, Moustafa A.
[1
,2
]
Abdel-Latief, Atta Y.
[1
,2
]
Mohamed, Ahmed Abdel-Rahim
[1
,2
]
Mojsilovic, Kristina
[3
]
Stepniowski, Wojciech Jerzy
[4
]
机构:
[1] Assiut Univ, Fac Sci, Phys Dept, Assiut 71516, Egypt
[2] Arab Republ Egypt, Acad Sci Res & Technol ASRT, Cairo 11516, Egypt
[3] Univ Belgrade, Fac Phys, Studentski Trg 12-16, Belgrade 11000, Serbia
[4] Mil Univ Technol, Fac Adv Technol & Chem, Inst Mat Sci & Engn, Kaliskiego 2 Str, PL-00908 Warsaw, Poland
来源:
关键词:
copper oxides;
anodization;
nanowires;
FTIR;
photocatalytic decolorization;
nanostructures;
tenorite;
cuprite;
paramelconite;
malachite;
TIO2;
PHOTOCATALYSIS;
CUO;
OXIDATION;
FILMS;
NANONEEDLE;
MECHANISM;
EFFICIENT;
KINETICS;
ARRAYS;
CARBON;
D O I:
10.3390/ma14175030
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
In recent paper anodization of copper foams in 0.1 M K2CO3 is reported. Anodization was performed in the voltage range of 5-25 V and in all the cases oxides with a developed surface area were obtained. However, anodizing only at 20 and 25 V resulted in the formation of nanostruc-tures. In all the cases, the products of anodizing consisted of crystalline phases like cuprite (Cu2O), tenorite (CuO), parameconite (Cu4O3) as well as spertiniite (Cu(OH)(2)). Copper foams after ano-dizing were applied as catalysts in the photocatalytic decolorization of a model organic compound such as methylene blue. The highest photocatalytic activity was observed for samples anodized at 25 V and closely followed by samples anodized at 5 V. The anodized copper foams proved to be a useful material in enhancing the photocatalytic efficiency of organic dye decomposition.
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页数:13
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