A porous metal-organic framework (MOF) with unusual 2D→3D polycatenation based on honeycomb layers

被引：57

作者：

Zhao, Xiaoliang ^{[1
]}

Dou, Jianmin ^{[2
]}

Sun, Di ^{[1
]}

Cui, Peipei ^{[1
]}

Sun, Daofeng ^{[1
]}

Wu, Qingyin ^{[3
]}

机构：

[1] Shandong Univ, Key Lab Colloid & Interface Chem, Minist Educ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China

[2] Liaocheng Univ, Dept Chem, Liaocheng 252059, Shandong, Peoples R China

[3] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China

来源：

DALTON TRANSACTIONS | 2012年 / 41卷 / 07期

关键词：

COORDINATION POLYMERS; MOLECULAR LADDERS; AROMATIC POLYCARBOXYLATE; PHYSICAL-PROPERTIES; HYDROGEN STORAGE; PI INTERACTIONS; LIGAND; NETWORKS; CRYSTAL; 2D;

D O I：

10.1039/c2dt11898j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel mixed-ligand 3D metal-organic framework (MOF), {Zn-2(TMTA)(bipy)(0.5)(H2O)(2)center dot NO3 center dot 2DMF center dot H2O}(n) (1) (H(3)TMTA = 4,4 ',4 ''-(2,4,6-trimethylbenzene-1,3,5-triyl)tribenzoic acid, bipy = 4,4 '-bipyridine, DMF = dimethylformamide), was constructed based on bipy-pillared honeycomb bilayers and showed the unusual 2D -> 3D polycatenation of bilayers.

引用

页码：1928 / 1930

页数：3

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