A porous metal-organic framework (MOF) with unusual 2D→3D polycatenation based on honeycomb layers

被引:57
|
作者
Zhao, Xiaoliang [1 ]
Dou, Jianmin [2 ]
Sun, Di [1 ]
Cui, Peipei [1 ]
Sun, Daofeng [1 ]
Wu, Qingyin [3 ]
机构
[1] Shandong Univ, Key Lab Colloid & Interface Chem, Minist Educ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China
[2] Liaocheng Univ, Dept Chem, Liaocheng 252059, Shandong, Peoples R China
[3] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China
关键词
COORDINATION POLYMERS; MOLECULAR LADDERS; AROMATIC POLYCARBOXYLATE; PHYSICAL-PROPERTIES; HYDROGEN STORAGE; PI INTERACTIONS; LIGAND; NETWORKS; CRYSTAL; 2D;
D O I
10.1039/c2dt11898j
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A novel mixed-ligand 3D metal-organic framework (MOF), {Zn-2(TMTA)(bipy)(0.5)(H2O)(2)center dot NO3 center dot 2DMF center dot H2O}(n) (1) (H(3)TMTA = 4,4 ',4 ''-(2,4,6-trimethylbenzene-1,3,5-triyl)tribenzoic acid, bipy = 4,4 '-bipyridine, DMF = dimethylformamide), was constructed based on bipy-pillared honeycomb bilayers and showed the unusual 2D -> 3D polycatenation of bilayers.
引用
收藏
页码:1928 / 1930
页数:3
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