Growth and characterization of pure and doped cadmium thiourea acetate single crystals

被引:17
作者
Kirupavathy, S. Shahil [1 ,2 ]
Mary, S. Stella [1 ,3 ]
Mythili, P. [1 ]
Gopalakrishnan, R. [1 ]
机构
[1] Anna Univ, Dept Phys, Madras 600025, Tamil Nadu, India
[2] Velammal Engn Coll, Dept Phys, Madras 600066, Tamil Nadu, India
[3] St Peters Engn Coll, Dept Phys, Madras 600054, Tamil Nadu, India
关键词
X-ray diffraction; growth from solution; dielectric constant; nonlinear optical crystal;
D O I
10.1016/j.jcrysgro.2008.01.020
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
Pure and doped (zinc acetate, N-methylurea and glycine) cadmium thiourea acetate single crystals were grown by slow evaporation solution growth method. The UV-visible, high-resolution X-ray diffraction and dielectric studies show the enhancement in the crystalline perfection of the glycine-doped cadmium thiourea acetate. The zinc acetate does not have significant effect on the structural and chemical properties, but has some effect on the electrical properties. However, the addition of N-methylurea activates the cadmium thiourea acetate ions, resulting in the decrease of the space charge polarization and increase in intrinsic defects. (C) 2008 Published by Elsevier B.V.
引用
收藏
页码:2555 / 2562
页数:8
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