Luminescent iridium complexes for detection of molybdate

被引：5

作者：

Castillo, Carmen E. ^{[2
,3
]}

Davies, David L. ^{[1
]}

Klair, Anne-K. Duhme ^{[2
]}

Singh, Kuldip ^{[1
]}

Singh, Shalini ^{[1
]}

机构：

[1] Univ Leicester, Dept Chem, Leicester LE1 7RH, Leics, England

[2] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England

[3] Univ Cadiz, Dept Ciencia Mat & Ingeniena Met & Quim Inorgan, Fac Ciencias, Cadiz, Spain

来源：

DALTON TRANSACTIONS | 2012年 / 41卷 / 02期

关键词：

METAL POLYPYRIDINE COMPLEXES; TRANSITION-METAL; SPECTROFLUOROMETRIC DETERMINATION; ENVIRONMENTAL-SAMPLES; CRYSTAL-STRUCTURE; POLYMERIC MATRIX; OXYGEN SENSORS; MOLYBDENUM; CHEMOSENSOR; RECEPTORS;

D O I：

10.1039/c1dt11360g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of [Ir((CN)-N-boolean AND)(2)Cl](2) [HCYN = 2-(3-R-phenyl) pyridine, 2-(3-R-phenylpyrazole) R = H, Me] with Me-2-phencat give luminescent complexes [Ir((CN)-N-boolean AND)(2)(Me-2-phencat)][PF6] (Me-2-2a, b, c)[PF6]. Deprotection of the methoxy groups with BBr3 is problematic as simultaneous bromination of the cyclometallated phenyl groups occurs. However, deprotection of Me-2-phencat with BBr3 followed by complexation with [Ir(CYN)(2)Cl](2) gives luminescent complexes [Ir((CN)-N-boolean AND)(2)(H-2-phencat)][PF6] (H-2-3a, c)[PF6], which are luminescent sensors for molybdate.

引用

页码：628 / 635

页数：8

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