Complexation with diol host compounds.: Part 35:: Inclusion compounds of 1,1,6,6-tetraphenylhexa-2,4-diyne-1,6-diol with CCl4, CHCl3, CH2Cl2 and CH3CN

被引：7

作者：

Caira, MR

Jacobs, A

Nassimbeni, LR

Toda, E

机构：

[1] Cape Technikon, ZA-8000 Cape Town, South Africa

[2] Univ Cape Town, Dept Chem, ZA-7701 Rondebosch, South Africa

[3] Okayama Univ Sci, Dept Chem, Okayama, Japan

来源：

SUPRAMOLECULAR CHEMISTRY | 2004年 / 16卷 / 02期

关键词：

inclusion compounds; clathrates; kinetics; isostructurality;

D O I：

10.1080/10610270310001607807

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Inclusion compounds were formed with 1,1,6,6-tetraphenylhexa-2,4-diyne-1,6-diol (H) and carbon tetrachloride, chloroform, dichloromethane and acetonitrile. 1 (H.1/2CCl(4)), 2 (H.1/2CHCl(3)) and 3 (H.1/2CH(2)Cl(2)) are true clathrates with the guest molecules situated in cages created by the host. 4 (H.2CH(3)CN) exhibits a different packing arrangement with the guest molecules located in channels. The crystal structures and stability of these inclusion compounds were investigated.

引用

页码：107 / 112

页数：6

共 14 条

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