Synthesis of nanoporous hypercrosslinked polyaniline (HCPANI) for gas sorption and electrochemical supercapacitor applications

被引:35
作者
Sharma, Vivek [1 ]
Sahoo, Asit [1 ]
Sharma, Yogesh [1 ]
Mohanty, Paritosh [1 ]
机构
[1] IIT Roorkee, Dept Appl Sci & Engn, Saharanpur 247001, India
关键词
HIGH-SURFACE-AREA; HYDROGEN STORAGE; POTENTIAL ADSORBENTS; POLYMER NETWORKS; CO2; CAPTURE; ELECTRODES; FRAMEWORKS; SIZE;
D O I
10.1039/c5ra03016a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Nanoporous hypercrosslinked polyaniline with SA(BET) of 1059 m(2) g(-1) has been synthesized. The specimen showed CO2 and CH4 uptake of 3.52 and 1.01 mmol g(-1), respectively at 273 K, and H-2 storage capacity of 1.85 wt% at 77 K and 1 bar. The material has a high specific capacitance of 410(+/- 5) F g(-1) and has shown good cyclability (100% retention) up to 1000 cycles.
引用
收藏
页码:45749 / 45754
页数:6
相关论文
共 34 条
[11]   Designing adsorbents for CO2 capture from flue gas-hyperbranched aminosilicas capable,of capturing CO2 reversibly [J].
Hicks, Jason C. ;
Drese, Jeffrey H. ;
Fauth, Daniel J. ;
Gray, McMahan L. ;
Qi, Genggeng ;
Jones, Christopher W. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (10) :2902-2903
[12]   SOLID-STATE C-13 NMR CHARACTERIZATION OF POLYANILINES [J].
KAPLAN, S ;
CONWELL, EM ;
RICHTER, AF ;
MACDIARMID, AG .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (23) :7647-7651
[13]   Relation between the ion size and pore size for an electric double-layer capacitor [J].
Largeot, Celine ;
Portet, Cristelle ;
Chmiola, John ;
Taberna, Pierre-Louis ;
Gogotsi, Yury ;
Simon, Patrice .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (09) :2730-+
[14]   Theoretical and experimental specific capacitance of polyaniline in sulfuric acid [J].
Li, Hanlu ;
Wang, Jixiao ;
Chu, Qingxian ;
Wang, Zhi ;
Zhang, Fengbao ;
Wang, Shichang .
JOURNAL OF POWER SOURCES, 2009, 190 (02) :578-586
[15]   Porous covalent electron-rich organonitridic frameworks as highly selective sorbents for methane and carbon dioxide [J].
Mohanty, Paritosh ;
Kull, Lilian D. ;
Landskron, Kai .
NATURE COMMUNICATIONS, 2011, 2
[16]   Hyperbranched polyaniline: A new conductive polyaniline with simultaneously good solubility and super high thermal stability [J].
Qiang, Zhixiang ;
Liang, Guozheng ;
Gu, Aijuan ;
Yuan, Li .
MATERIALS LETTERS, 2014, 115 :159-161
[17]   Design and synthesis of novel carbazole-spacer-carbazole type conjugated microporous networks for gas storage and separation [J].
Qiao, Shanlin ;
Du, Zhengkun ;
Yang, Renqiang .
JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (06) :1877-1885
[18]   High CO2 uptake and selectivity by triptycene-derived benzimidazole-linked polymers [J].
Rabbani, Mohammad Gulam ;
Reich, Thomas E. ;
Kassab, Refaie M. ;
Jackson, Karl T. ;
El-Kaderi, Hani M. .
CHEMICAL COMMUNICATIONS, 2012, 48 (08) :1141-1143
[19]   Click-based porous inorganic-organic hybrid material (PHM) containing cyclophosphazene unit and their application in carbon dioxide capture [J].
Rekha, Pawan ;
Sahoo, Usharani ;
Mohanty, Paritosh .
RSC ADVANCES, 2014, 4 (66) :34860-34863
[20]   Hybrid materials of polyaniline and acidic hexaniobate nanoscrolls: high polaron formation and improved thermal properties [J].
Silva, Claudio H. B. ;
Da Costa Ferreira, Ana M. ;
Constantino, Vera R. L. ;
Temperini, Marcia L. A. .
JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (22) :8205-8214