Synthesis of nanoporous hypercrosslinked polyaniline (HCPANI) for gas sorption and electrochemical supercapacitor applications

被引:35
作者
Sharma, Vivek [1 ]
Sahoo, Asit [1 ]
Sharma, Yogesh [1 ]
Mohanty, Paritosh [1 ]
机构
[1] IIT Roorkee, Dept Appl Sci & Engn, Saharanpur 247001, India
关键词
HIGH-SURFACE-AREA; HYDROGEN STORAGE; POTENTIAL ADSORBENTS; POLYMER NETWORKS; CO2; CAPTURE; ELECTRODES; FRAMEWORKS; SIZE;
D O I
10.1039/c5ra03016a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Nanoporous hypercrosslinked polyaniline with SA(BET) of 1059 m(2) g(-1) has been synthesized. The specimen showed CO2 and CH4 uptake of 3.52 and 1.01 mmol g(-1), respectively at 273 K, and H-2 storage capacity of 1.85 wt% at 77 K and 1 bar. The material has a high specific capacitance of 410(+/- 5) F g(-1) and has shown good cyclability (100% retention) up to 1000 cycles.
引用
收藏
页码:45749 / 45754
页数:6
相关论文
共 34 条
[1]   Nanostructured crosslinked polyaniline with high surface area: Synthesis, characterization and adsorption for organic dye [J].
Ayad, Mohamad ;
Zaghlol, Sawsan .
CHEMICAL ENGINEERING JOURNAL, 2012, 204 :79-86
[2]   The potential of organic polymer-based hydrogen storage materials [J].
Budd, Peter M. ;
Butler, Anna ;
Selbie, James ;
Mahmood, Khalid ;
McKeown, Neil B. ;
Ghanem, Bader ;
Msayib, Kadhum ;
Book, David ;
Walton, Allan .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2007, 9 (15) :1802-1808
[3]   Electrospun polyaniline nanofibers web electrodes for supercapacitors [J].
Chaudhari, Sudeshna ;
Sharma, Yogesh ;
Archana, Panikar Sathyaseelan ;
Jose, Rajan ;
Ramakrishna, Seeram ;
Mhaisalkar, Subodh ;
Srinivasan, Madhavi .
JOURNAL OF APPLIED POLYMER SCIENCE, 2013, 129 (04) :1660-1668
[4]   Microporous Polycarbazole with High Specific Surface Area for Gas Storage and Separation [J].
Chen, Qi ;
Luo, Min ;
Hammershoj, Peter ;
Zhou, Ding ;
Han, Ying ;
Laursen, Bo Wegge ;
Yan, Chao-Guo ;
Han, Bao-Hang .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (14) :6084-6087
[5]   Spiro(fluorene-9,9′-xanthene)-Based Porous Organic Polymers: Preparation, Porosity, and Exceptional Hydrogen Uptake at Low Pressure [J].
Chen, Qi ;
Wang, Jin-Xiang ;
Wang, Qiu ;
Bian, Ning ;
Li, Zhong-Hua ;
Yan, Chao-Guo ;
Han, Bao-Hang .
MACROMOLECULES, 2011, 44 (20) :7987-7993
[6]   Morphology-Dependent Enhancement of the Pseudocapacitance of Template-Guided Tunable Polyaniline Nanostructures [J].
Chen, Wei ;
Rakhi, R. B. ;
Alshareef, H. N. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2013, 117 (29) :15009-15019
[7]   Carbon Dioxide Capture: Prospects for New Materials [J].
D'Alessandro, Deanna M. ;
Smit, Berend ;
Long, Jeffrey R. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (35) :6058-6082
[8]   The Chemistry and Applications of Metal-Organic Frameworks [J].
Furukawa, Hiroyasu ;
Cordova, Kyle E. ;
O'Keeffe, Michael ;
Yaghi, Omar M. .
SCIENCE, 2013, 341 (6149) :974-+
[9]   Preparation of Size-Selective Nanoporous Polymer Networks of Aromatic Rings: Potential Adsorbents for Hydrogen Storage [J].
Germain, Jonathan ;
Svec, Frantisek ;
Frechet, Jean M. J. .
CHEMISTRY OF MATERIALS, 2008, 20 (22) :7069-7076
[10]   Hypercrosslinked polyanilines with nanoporous structure and high surface area:: potential adsorbents for hydrogen storage [J].
Germain, Jonathan ;
Frechet, Jean M. J. ;
Svec, Frantisek .
JOURNAL OF MATERIALS CHEMISTRY, 2007, 17 (47) :4989-4997