Rational Design of Two-Dimensional Bimetallic Wave Structures from Zigzag Chains via Site-Specific Coordination around the 2,6-Naphthalenediphosphonic Acid Motif

被引：14

作者：

Bulut, Aysun ^{[1
,2
]}

Zorlu, Yunus ^{[3
]}

Worle, Michael ^{[4
]}

Pasa, Salih ^{[5
]}

Kurt, Huseyin ^{[6
]}

Zubieta, Jon ^{[7
]}

Beckmann, Jens ^{[8
]}

Yucesan, Gundog ^{[1
]}

机构：

[1] Yildiz Tech Univ, Dept Bioengn, Davutpasa Cad 127, TR-34210 Istanbul, Turkey

[2] Istanbul Kemerburgaz Univ, Fac Pharm, Istanbul, Turkey

[3] Gebze Tech Univ, Dept Chem, TR-41400 Gebze, Turkey

[4] ETH, Inorgan Chem Lab, HCI H103 Vladimir Prelog Weg, CH-8093 Zurich, Switzerland

[5] Afyon Kocatepe Univ, Fac Educ, TR-03000 Afyon, Turkey

[6] Istanbul Medeniyet Univ, Dept Engn Phys, Istanbul, Turkey

[7] Syracuse Univ, Ctr Sci & Technol, Syracuse, NY 13244 USA

[8] Univ Bremen, Inst Anorgan Chem & Kristallog, D-28359 Bremen, Germany

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2016年 / 21期

关键词：

Metal-organic frameworks; Metal-organic solids; Organophosphonates; Ligand design; Coordination modes; Copper; Magnetic properties; METAL-ORGANIC FRAMEWORKS; CRYSTAL-STRUCTURES; TEMPERATURE-DEPENDENCE; HYDROTHERMAL SYNTHESIS; 1ST ROUTE; CHEMISTRY; PHOSPHONATE; LIGANDS; SYSTEM; LAYERS;

D O I：

10.1002/ejic.201600309

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We report the synthesis of a novel aromatic 2,6-naphthalenediphosphonic acid (2,6-NDPA-H-4) and the rational design of molecular, one-, two-, and three-dimensional structures of the resulting copper organophosphonate materials: [{Cu(terpy)}(2,6-NDPA-H-3)][{Cu(terpy)}(2,6-NDPA-H-3)(2,6-NDPA-H-2)]center dot 3H(2)O (2), [{Cu(terpy)}VO2(2,6-NDPA-H)]center dot H2O (4), [{Cu-(terpy)} VO2(2,6-NDPA-H)] (3) and [{Cu(H2O)}(NDPA)(0.5)] (1). Engineering the copper coordination sphere and pH-controlled phosphonate protonation enabled the site specific dimensional evolution of CuII-organophosphonate frameworks exploiting the 2deprotonated phosphonate oxygen arms.

引用

页码：3506 / 3512

页数：7

共 47 条

[1] SYNTHESIS, STRUCTURE, AND SPECTROSCOPIC PROPERTIES OF COPPER(II) COMPOUNDS CONTAINING NITROGEN SULFUR DONOR LIGANDS - THE CRYSTAL AND MOLECULAR-STRUCTURE OF AQUA[1,7-BIS(N-METHYLBENZIMIDAZOL-2'-YL)-2,6-DITHIAHEPTANE]COPPER(II) PERCHLORATE [J].

ADDISON, AW ;

RAO, TN ;

REEDIJK, J ;

VANRIJN, J ;

VERSCHOOR, GC .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (07) :1349-1356

[2] Chains, Layers, Channels, and More: Supramolecular Chemistry of Potent Diphosphonic Tectons with Tuned Flexibility. The Generation of Pseudopolymorphs, Polymorphs, and Adducts [J].

Bialek, Michal J. ;

Zareba, Jan K. ;

Janczak, Jan ;

Zon, Jerzy .

CRYSTAL GROWTH & DESIGN, 2013, 13 (09) :4039-4050

[3] Naphthalene-based linkers for metal phosphonates: synthesis, structure, and interesting conformational flexibility influence on final lanthanum hybrids [J].

Bialek, Michal J. ;

Janczak, Jan ;

Zon, Jerzy .

CRYSTENGCOMM, 2013, 15 (02) :390-399

[4]

Blatov V. A., TOPOS PROFESSIONAL V

[5] SYNTHESIS OF NEW LAMELLAR IRON(III) PHOSPHONATES [J].

BUJOLI, B ;

PALVADEAU, P ;

ROUXEL, J .

CHEMISTRY OF MATERIALS, 1990, 2 (05) :582-589

[6] Solid state coordination chemistry of oxomolybdenum organoarsonate materials [J].

Burkholder, E ;

Wright, S ;

Golub, V ;

O'Connor, CJ ;

Zubieta, J .

INORGANIC CHEMISTRY, 2003, 42 (23) :7460-7471

[7] Synthesis and structure of the two-dimensional bimetallic oxide [H4tphz]3[{Zn2(tphz)(H2O)4}{Mo5O15(O3PCH2CH2PO3)}4] • 14H2O:: the hydrothermal conversion of tetra-2-pyridylpyrazine to tetrapyrido [2,3-a:3′,2′-c:2",3"-h:3"′,2"′-j]phenazine (tphz) [J].

Burkholder, E ;

Zubieta, J .

INORGANICA CHIMICA ACTA, 2004, 357 (04) :1229-1235

[8] STRUCTURAL STUDIES OF ORIENTED ZIRCONIUM BIS(PHOSPHONOACETIC ACID) USING SOLID-STATE P-31 AND C-13 NMR [J].

BURWELL, DA ;

VALENTINE, KG ;

TIMMERMANS, JH ;

THOMPSON, ME .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (11) :4144-4150

[9] Crystal structure of a porous zirconium phosphate/phosphonate compound and photocatalytic hydrogen production from related materials [J].

Byrd, H ;

Clearfield, A ;

Poojary, D ;

Reis, KP ;

Thompson, ME .

CHEMISTRY OF MATERIALS, 1996, 8 (09) :2239-2246

[10] SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF A HOMOLOGOUS SERIES OF DIVALENT-METAL PHOSPHONATES, MII(O3PR).H2O AND MII(HO3PR)2 [J].

CAO, G ;

LEE, H ;

LYNCH, VM ;

MALLOUK, TE .

INORGANIC CHEMISTRY, 1988, 27 (16) :2781-2785

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