Stability of Crystalline Gd2O3 Thin Films on Silicon during Post-growth Processing

被引:0
作者
Schwendt, D. [1 ]
Tetzlaff, D. [1 ]
Bugiel, E. [1 ]
Osten, H. J. [1 ]
Gottlob, H. D. B. [2 ]
机构
[1] Leibniz Univ Hannover, Inst Elect Mat & Devices, Hannover, Germany
[2] AMO GmbH, Aachen, Germany
来源
2009 3RD INTERNATIONAL CONFERENCE ON SIGNALS, CIRCUITS AND SYSTEMS (SCS 2009) | 2009年
关键词
High-K dielectrics; gadolinium oxide; temperature stability; forming gas anneal; gadolinium silicate; MOSFETS; LAYERS;
D O I
暂无
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
Experimental results for crystalline Gd2O3-based MOS capacitors show that these layers are excellent candidates for application as very thin high-K materials replacing SiO2 in future MOS devices. First electrical characteristics of n- and p-type SOI-MOSFETs with epitaxial Gd2O3 demonstrate the general feasibility of this novel gate insulator, but thermal stability during typical CMOS annealing processes has been identified as a key issue. Here, we investigate the effect of post-growth annealing on layer properties. Standard forming gas anneal can eliminate flatband instabilities and hysteresis as well as reduce leakage currents by saturating dangling bond caused by the bonding mismatch. In addition, we investigated the impact of rapid thermal anneals on structural and electrical properties of crystalline Gd2O3 layers grown on Si. Finally, we will show a new way to improve the thermal stability of those crystalline layers significantly.
引用
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页码:28 / +
页数:2
相关论文
共 14 条
[1]  
Adachi G, 2004, BINARY RARE EARTH OXIDES, P1
[2]   Impact of oxygen supply during growth on the electrical properties of crystalline Gd2O3 thin films on Si(001) [J].
Czernohorsky, M ;
Bugiel, E ;
Osten, HJ ;
Fissel, A ;
Kirfel, O .
APPLIED PHYSICS LETTERS, 2006, 88 (15)
[3]   Stability of crystalline Gd2O3 thin films on silicon during rapid thermal annealing [J].
Czernohorsky, M. ;
Tetzlaff, D. ;
Bugiel, E. ;
Dargis, R. ;
Osten, H. J. ;
Gottlob, H. D. B. ;
Schmidt, M. ;
Lemme, M. C. ;
Kurz, H. .
SEMICONDUCTOR SCIENCE AND TECHNOLOGY, 2008, 23 (03)
[4]   Investigation of MOS capacitors and SOI-MOSFETs with epitaxial gadolinium oxide (Gd2O3) and titanium nitride (TiN) electrodes [J].
Echtermeyer, T. ;
Gottlob, H. D. B. ;
Wahlbrink, T. ;
Mollenhauer, T. ;
Schmidt, M. ;
Efavi, J. K. ;
Lemme, M. C. ;
Kurz, H. .
SOLID-STATE ELECTRONICS, 2007, 51 (04) :617-621
[5]   Electrical characterization of crystalline Gd2O3 gate dielectric MOSFETs fabricated by damascene metal gate technology [J].
Endres, Ralf ;
Stefanov, Yordan ;
Schwalke, Udo .
MICROELECTRONICS RELIABILITY, 2007, 47 (4-5) :528-531
[6]   Gentle FUSI NiSi metal gate process for high-k dielectric screening [J].
Gottlob, H. D. B. ;
Lemme, M. C. ;
Schmidt, M. ;
Echtermeyer, T. J. ;
Mollenhauer, T. ;
Kurz, H. ;
Cherkaoui, K. ;
Hurley, P. K. ;
Newcomb, S. B. .
MICROELECTRONIC ENGINEERING, 2008, 85 (10) :2019-2021
[7]   0.86-nm CET gate stacks with epitaxial Gd2O3 high-k dielectrics and FUSINiSi metal electrodes [J].
Gottlob, H. D. B. ;
Echtermeyer, T. ;
Schmidt, M. ;
Mollenhauer, T. ;
Efavi, J. K. ;
Wahlbrink, T. ;
Lemme, M. C. ;
Czernohorsky, M. ;
Bugiel, E. ;
Fissel, A. ;
Osten, H. J. ;
Kurz, H. .
IEEE ELECTRON DEVICE LETTERS, 2006, 27 (10) :814-816
[8]   Ultrathin (<4 nm) SiO2 and Si-O-N gate dielectric layers for silicon microelectronics:: Understanding the processing, structure, and physical and electrical limits [J].
Green, ML ;
Gusev, EP ;
Degraeve, R ;
Garfunkel, EL .
JOURNAL OF APPLIED PHYSICS, 2001, 90 (05) :2057-2121
[9]   Influence of interface layer composition on the electrical properties of epitaxial Gd2O3 thin films for high-K application [J].
Laha, Apurba ;
Osten, H. J. ;
Fissel, A. .
APPLIED PHYSICS LETTERS, 2007, 90 (11)
[10]   Dielectric properties of Pr2O3 high-k films grown by metalorganic chemical vapor deposition on silicon [J].
Lo Nigro, R ;
Raineri, V ;
Bongiorno, C ;
Toro, R ;
Malandrino, G ;
Fragalá, IL .
APPLIED PHYSICS LETTERS, 2003, 83 (01) :129-131