Hydrothermal synthesis and characterization of a Na+ templated new 3-D lanthanum sulfate Na[C6H14N2][La3(SO4)6(H2O)3] constructed from La-O-S tubes and cubic cages

被引：16

作者：

Zheng, Lei ^{[1
]}

Zhang, Zhibin ^{[1
,2
]}

Zhu, Dunru ^{[1
]}

Xu, Yan ^{[1
]}

机构：

[1] Nanjing Univ Technol, Coll Chem & Chem Engn, State Key Lab Mat Oriented Chem Engn, Nanjing 210009, Peoples R China

[2] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2011年 / 14卷 / 01期

基金：

中国国家自然科学基金;

关键词：

Hydrothermal synthesis; Lanthanum sulfates; Crystal structures; 3D framework; Template; CRYSTAL-STRUCTURE; SOLVOTHERMAL SYNTHESIS; METAL SULFATES; ANIONS; 3D;

D O I：

10.1016/j.inoche.2010.11.008

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new lanthanum sulfate Na[C6H14N2][La-3(SO4)(6)(H2O)(3)] 1 has been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction, IR and TGA. Structure analysis indicates that the structure of 1 features unusual three-dimensional inorganic framework constructed from La-O-S tubes and cubic cages. The Na+ plays an important role in the formation of 3-D open framework of 1. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：258 / 260

页数：3

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