Metal-directed self-assembly of bimetallic dithiocarbamate transition metal cryptands and their binding capabilities

被引：71

作者：

Beer, PD ^{[1
]}

Berry, NG ^{[1
]}

Cowley, AR ^{[1
]}

Hayes, EJ ^{[1
]}

Oates, EC ^{[1
]}

Wong, WWH ^{[1
]}

机构：

[1] Univ Oxford, Inorgan Chem Lab, Dept Chem, Oxford OX1 3QR, England

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 19期

关键词：

D O I：

10.1039/b308629a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel family of redox-active dinuclear transition metal based cryptands self-assembled from dithiocarbarnate ligands has been synthesised; depending upon the nature of the spacer groups these new cryptand systems have been shown to electrochemically recognise the binding of cations or anions.

引用

页码：2408 / 2409

页数：2

共 13 条

[1] Mechanisms of electrochemical recognition of cations, anions and neutral guest species by redox-active receptor molecules [J].

Beer, PD ;

Gale, PA ;

Chen, GZ .

COORDINATION CHEMISTRY REVIEWS, 1999, 185-6 :3-36

[2] Self-assembled dithiocarbamate-copper(II) macrocycles for electrochemical anion recognition [J].

Beer, PD ;

Berry, N ;

Drew, MGB ;

Fox, OD ;

Padilla-Tosta, ME ;

Patell, S .

CHEMICAL COMMUNICATIONS, 2001, (02) :199-200

[3] Pyrrole-based metallo-macrocycles and cryptands [J].

Beer, PD ;

Cheetham, AG ;

Drew, MGB ;

Fox, OD ;

Hayes, EJ ;

Rolls, TD .

DALTON TRANSACTIONS, 2003, (04) :603-611

[4] STRUCTURAL STUDIES OF METAL DITHIOCARBAMATES .1. CRYSTAL AND MOLECULAR STRUCTURE OF THE ALPHA FORM OF NICKEL DIETHYLDITHIOCARBAMATE [J].

BONAMICO, M ;

DESSY, G ;

MARIANI, C ;

VACIAGO, A ;

ZAMBONEL.L .

ACTA CRYSTALLOGRAPHICA, 1965, 19 :619-+

[5] SULFUR CHELATES .16. CHEMICAL PROPERTIES OF OXIDIZED NICKEL(II) DITHIOCARBAMATES - X-RAY CRYSTAL-STRUCTURE OF TRIS(N,N-DI-N-BUTYLDITHIOCARBAMATO)NICKEL(IV) BROMIDE, NIC27H54N3S6BR [J].

FACKLER, JP ;

AVDEEF, A ;

FISCHER, RG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (03) :774-782

[6]

Fox OD, 2000, ANGEW CHEM INT EDIT, V39, P136

[7] Metal-directed self-assembly of two- and three-dimensional synthetic receptors [J].

Fujita, M .

CHEMICAL SOCIETY REVIEWS, 1998, 27 (06) :417-425

[8]

Jones CJ, 1998, CHEM SOC REV, V27, P289

[9] STRUCTURE OF THE BETA-FORM OF BIS(DIETHYLDITHIOCARBAMATO)NICKEL(II) [J].

KHAN, MNI ;

FACKLER, JP ;

MURRAY, HH ;

HEINRICH, DD .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1987, 43 :1917-1919

[10] Self-assembly of discrete cyclic nanostructures mediated by transition metals [J].

Leininger, S ;

Olenyuk, B ;

Stang, PJ .

CHEMICAL REVIEWS, 2000, 100 (03) :853-907

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