Experimental evaluation of Sarcosine as an eco-friendly green hydrate inhibitor for the drilling of gas hydrate bearing formations

The hydrate inhibitors played a significant role in preventing hydrate formation in the drilling fluid systems. However, the disposal of these inhibitors was the primary concern for the drilling industries, as Thermodynamic Hydrate Inhibitors (THIs) are not eco-friendly, and Kinetic Hydrate Inhibitors (KHIs) are troublesome to dispose of due to their long polymeric structures. Hence, an attempt had been made to evaluate the Sarcosine, an amino acid, as a biodegradable, green hydrate inhibitor for water-based drilling fluid systems. Initial screening of Sarcosine in the THF-water hydrate (structure-II) system showed that it behaved as a zwitterionic, dual-function inhibitor. It had better inhibition characteristics in delaying induction time and improving rheological and filtration properties than PVCap and PVP while used in formulated mud compositions. The water-based mud used in this work was prepared by mixing carboxymethyl cellulose (CMC), polyanionic cellulose (PAC), xanthan gum (XG), and potassium chloride (KCl) with distilled water. For Sarcosine content water-based mud systems, coefficients of determination (R2) values were dependable, while low-temperature (2 C) rheological values were fitted in Herschel-Bulkley model. These experimental investigations showed that the Sarcosine might be used for the drilling of gas hydrate-bearing formations.