Elastic properties of monolayers of soluble surfactants at oil-brine interfaces

被引:17
作者
Kellay, H
Meunier, J
机构
[1] UNIV PARIS 06,ENS,LAB PHYS STAT,CNRS,URA 1306,F-75231 PARIS 05,FRANCE
[2] UNIV PARIS 07,F-75231 PARIS 05,FRANCE
关键词
D O I
10.1088/0953-8984/8/25A/005
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
The microstructure of microemulsions and related systems diluted in surfactant is determined in a first approximation via the characteristics of the surfactant monolayer: the bending elastic modulus, K, the saddle splay modulus, (K) over bar and the spontaneous curvature C-0. The methods which were developed to measure these quantities in Winsor equilibrium (microemulsions or related systems in equilibrium with an excess of oil or brine) are discussed. Results concerning various surfactants are given and compared with the results obtained for similar systems with other techniques. It is also shown how these results explain the observed phase structures.
引用
收藏
页码:A49 / A64
页数:16
相关论文
共 56 条
  • [41] MEUNIER J, 1989, SURFACTANTS SOLUTION, V9, P463
  • [42] CURVATURE ELASTICITY OF CHARGED MEMBRANES
    MITCHELL, DJ
    NINHAM, BW
    [J]. LANGMUIR, 1989, 5 (04) : 1121 - 1123
  • [43] EFFECTS OF THERMAL FLUCTUATIONS ON SYSTEMS WITH SMALL SURFACE-TENSION
    PELITI, L
    LEIBLER, S
    [J]. PHYSICAL REVIEW LETTERS, 1985, 54 (15) : 1690 - 1693
  • [44] ORIGIN OF LOW INTERFACIAL-TENSIONS IN SYSTEMS INVOLVING MICRO-EMULSION PHASES
    POUCHELON, A
    CHATENAY, D
    MEUNIER, J
    LANGEVIN, D
    [J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1981, 82 (02) : 418 - 422
  • [45] POUCHELON A, 1980, J PHYS LETT-PARIS, V41, pL239, DOI 10.1051/jphyslet:019800041010023900
  • [46] STABILITY OF MICROEMULSIONS
    RUCKENSTEIN, E
    CHI, JC
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS II, 1975, 71 : 1690 - 1707
  • [47] STERIC INTERACTIONS IN A MODEL MULTIMEMBRANE SYSTEM - A SYNCHROTRON X-RAY STUDY
    SAFINYA, CR
    ROUX, D
    SMITH, GS
    SINHA, SK
    DIMON, P
    CLARK, NA
    BELLOCQ, AM
    [J]. PHYSICAL REVIEW LETTERS, 1986, 57 (21) : 2718 - 2721
  • [48] MAGNETIC-FIELD-INDUCED ORIENTATION AND BENDING OF THE MYELIN FIGURES OF PHOSPHATIDYLCHOLINE
    SAKURAI, I
    KAWAMURA, Y
    [J]. BIOCHIMICA ET BIOPHYSICA ACTA, 1983, 735 (01) : 189 - 192
  • [49] THERMAL FLUCTUATIONS OF LARGE QUASI-SPHERICAL BIMOLECULAR PHOSPHOLIPID-VESICLES
    SCHNEIDER, MB
    JENKINS, JT
    WEBB, WW
    [J]. JOURNAL DE PHYSIQUE, 1984, 45 (09): : 1457 - 1472
  • [50] EQUILIBRIUM BICONTINUOUS STRUCTURE
    SCRIVEN, LE
    [J]. NATURE, 1976, 263 (5573) : 123 - 125