Chloridobis(1,10-phenanthroline-κ2N,N′)copper(I) dichloridocopper(II)

被引：4

作者：

Meng, Qingfen ^{[1
,2
]}

Chen, Yanmei ^{[2
]}

Li, Bing ^{[1
]}

Chen, Sanping ^{[1
]}

Gao, Shengli ^{[1
]}

机构：

[1] NW Univ Xian, Dept Chem, Xian 710069, Peoples R China

[2] Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 818008, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷

基金：

美国国家科学基金会;

关键词：

PHENANTHROLINE; COMPLEX; CL;

D O I：

10.1107/S1600536810054073

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The asymmetric unit of the title compound, [CuCl(C12H8N2)(2)]center dot[CuCl2], contains two complex Cu(II) cations and two cuprate(I) anions. The Cu(II) atom is coordinated by two phenanthroline (phen) molecules and one chloride anion in a distorted trigonal-bipyramidal geometry. The Cu(II) complex cations form layers through pi-pi stacking [interplanar distance = 3.481 (2) angstrom]. The dichloridocuprate(I) anions are located between the layers, forming a sandwich-like structure.

引用

页码：M226 / U1088

页数：15

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