Electrospun membrane of cellulose acetate for heavy metal ion adsorption in water treatment

被引:242
作者
Tian, Ye [2 ]
Wu, Min [1 ]
Liu, Ruigang [2 ]
Li, Yanxiang [2 ,3 ]
Wang, Deqian [2 ,3 ]
Tan, Junjun [2 ,3 ]
Wu, Rongcheng [5 ]
Huang, Yong [1 ,2 ,4 ]
机构
[1] Chinese Acad Sci, State Engn Res Ctr Engn Plast, Tech Inst Phys & Chem, Beijing 100190, Peoples R China
[2] Chinese Acad Sci, State Key Lab Polymer Phys & Chem, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China
[3] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
[4] Chinese Acad Sci, Lab Cellulose & Lignocellulos Chem, Guangzhou Inst Chem, Guangzhou 510650, Guangdong, Peoples R China
[5] Beijing China Sci Environm Protect Co Ltd, Beijing 100080, Peoples R China
关键词
Electrospinning; Metal ions; Cellulose acetate; Water treatment; WASTE-WATER; GRAFT-COPOLYMERIZATION; REMOVAL; ADSORBENTS; COPPER; BLEND;
D O I
10.1016/j.carbpol.2010.08.054
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Cellulose acetate (CA) nonwoven membrane for heavy metal ion adsorption was prepared by electrospinning and surface modification with poly(methacrylic acid) (PMAA) The morphology and graft modification of the membrane were characterized by SEM and ATR-FTIR The adsorption of heavy metal ions Cu2+ Hg2+ and Cd2+ on this membrane was investigated The adsorption capacity increased with the increasing of initial pH value in the system This membrane has quite high adsorption selectivity for Hg2+ The adsorbed metal ions can be easily de-adsorbed from the membrane surface by using saturated ethylenedinitrilo tetraacetic acid solution and can be re-used for the metal ion adsorption (C) 2010 Elsevier Ltd All rights reserved
引用
收藏
页码:743 / 748
页数:6
相关论文
共 30 条
[1]   The removal of heavy-metal ions by seaweeds and their derivatives [J].
Aderhold, D ;
Williams, CJ ;
Edyvean, RGJ .
BIORESOURCE TECHNOLOGY, 1996, 58 (01) :1-6
[2]   SH-containing cellulose acetate derivatives: Preparation and characterization as a shape memory-recovery material [J].
Aoki, Dan ;
Teramoto, Yoshikuni ;
Nishio, Yoshiyuki .
BIOMACROMOLECULES, 2007, 8 (12) :3749-3757
[3]   Ammonium removal from aqueous solutions by reverse osmosis using cellulose acetate membranes [J].
Bódalo, A ;
Gómez, JL ;
Gómez, E ;
León, G ;
Tejera, M .
DESALINATION, 2005, 184 (1-3) :149-155
[4]   A submerged nanofiltration membrane bioreactor for domestic wastewater treatment: the performance of cellulose acetate nanofiltration membranes for long-term operation [J].
Choi, Jae-Hoon ;
Fukushi, Kensuke ;
Yamamoto, Kazuo .
SEPARATION AND PURIFICATION TECHNOLOGY, 2007, 52 (03) :470-477
[5]   Spinning continuous fibers for nanotechnology [J].
Dzenis, Y .
SCIENCE, 2004, 304 (5679) :1917-1919
[6]  
FRIBERG LT, 1985, AM IND HYG ASSOC J, V46, P633, DOI 10.1202/0002-8894(1985)046<0633:TROBMO>2.3.CO
[7]  
2
[8]  
(Fujf) F P F C L, 2003, PROC AG US SILV HAL
[9]   Temperature-responsive cellulose by ceric(IV) ion-initiated graft copolymerization of N-isopropylacrylamide [J].
Gupta, KC ;
Khandekar, K .
BIOMACROMOLECULES, 2003, 4 (03) :758-765
[10]   Graft copolymerization of acrylonitrile and ethyl methacrylate comonomers on cellulose using ceric ions [J].
Gupta, KC ;
Sahoo, S .
BIOMACROMOLECULES, 2001, 2 (01) :239-247