共 152 条
Recent advances in Palladium(II)-catalyzed activation of aromatic ring C-H bonds
被引:32
作者:
Yun, Yin-ling
[1
,2
,3
,4
]
Yang, Jie
[1
,2
,3
,4
]
Miao, Yu-hang
[1
,2
,3
,4
]
Sun, Jie
[3
,4
,5
]
Wang, Xiao-jing
[3
,4
,5
]
机构:
[1] Univ Jinan, Shandong Acad Med Sci, Sch Med & Life Sci, Jinan 250200, Shandong, Peoples R China
[2] Shandong Acad Med Sci, Inst Mat Med, Jinan 250062, Shandong, Peoples R China
[3] Minist Hlth, Key Lab Biotech Drugs, Jinan 250062, Shandong, Peoples R China
[4] Key Lab Rare & Uncommon Dis Shandong Prov, Jinan 250062, Shandong, Peoples R China
[5] Shandong First Med Univ & Shandong Acad Med Sci, Inst Mat Med, Jinan, Peoples R China
关键词:
Aromatic ring C-H bonds;
Palladium catalyst;
Direct conversion;
CATALYZED ORTHO-ARYLATION;
SIMPLE ARENES;
ORTHO-HYDROXYLATION;
ORTHO-ALKOXYLATION;
INTRAMOLECULAR AMINATION;
C3-SELECTIVE ARYLATION;
ORTHO-OLEFINATION;
C(SP(2))-H BONDS;
FACILE SYNTHESIS;
ORTHO-ACYLATION;
D O I:
10.1016/j.jscs.2020.01.004
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
Palladium is a precious metal, which has been widely used for various organic transformations in the past decades. Currently, the palladium-catalyzed direct activation of the aromatic ring C-H bonds is one of the frontier areas in organic chemistry, and the progress of research in this field is very rapid. Compared with other transition metals, palladium has the advantages of high catalytic activity and strong selectivity. Combining the domestic and foreign scholars' research on this aspect, this paper summarizes the research progress of the palladium-catalyzed activation of aromatic ring C-H bonds in the past ten years. (C) 2020 King Saud University. Published by Elsevier B.V.
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页码:151 / 185
页数:35
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