Syntheses of penta-O-benzyl-myo-inositols, O-β-L-arabinosyl-(1→2)-sn-myo-inositol, O-α-D-galactosyl-(1→3)-sn-myo-inositol, and O-α-D-galactosyl-(1→6)-O-α-D-galactosyl-(1→3)-sn-myo-inositol

被引:12
作者
Koto, S [1 ]
Hirooka, M
Yoshida, T
Takenaka, K
Asai, C
Nagamitsu, T
Sakuma, H
Sakurai, M
Masuzawa, S
Komiya, M
Sato, T
Zen, S
Yago, K
Tomonaga, F
机构
[1] Kitasato Univ, Sch Pharmaceut Sci, Minato Ku, Tokyo 1088641, Japan
[2] Kitasato Univ Hosp, Dept Pharm, Sagamihara, Kanagawa 2288555, Japan
关键词
D O I
10.1246/bcsj.73.2521
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Two-step conversions of myo-inositol into (+/-)-2,3,4,5,6- and 1,3,4,5,6-penta-0-benzyl-myo-inositols are described. Starting from these monohydroxy derivatives of myo-inositol, O-beta -L-arabinopyranosyl-(1-->2)-sn-myo-inositol from Japanese green tea [], Camellia sinensis, and O-alpha -D-galactopyranosyl-(1-->3)-sn-myo-inositol (galactinol) as well as its homolog, O-alpha -D-galactopyranosy1-(1-->6(II))-galactinol, were synthesized by way of the in situ activating glycosylation procedure.(##)
引用
收藏
页码:2521 / 2529
页数:9
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