Synthesis and characterization of amylose grafted poly(acrylic acid) and its application in ammonia adsorption

被引：37

作者：

Chen, Qing ^{[1
]}

Yu, Haojie ^{[1
]}

Wang, Li ^{[1
]}

Zain-ul Abdin ^{[1
]}

Yang, Xinpeng ^{[1
]}

Wang, Junhua ^{[1
]}

Zhou, Weidong ^{[1
]}

Zhang, Hongtao ^{[2
]}

Chen, Xiao ^{[2
]}

机构：

[1] Zhejiang Univ, Coll Chem & Biol Engn, State Key Lab Chem Engn, Hangzhou 310027, Zhejiang, Peoples R China

[2] China Tobacco Henan Ind Co Ltd, Zhengzhou 450000, Peoples R China

来源：

CARBOHYDRATE POLYMERS | 2016年 / 153卷

关键词：

Amylose; Graft copolymer; Ammonia adsorption; Cigarette smoke; ACRYLIC-ACID; CHEMICAL-MODIFICATION; AQUEOUS-SOLUTION; CIGARETTE-SMOKE; POROUS STARCH; REMOVAL; AMYLOPECTIN;

D O I：

10.1016/j.carbpol.2016.07.120

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Amylose grafted poly(acrylic acid) (Am-g-PAA) was synthesized by graft copolymerization of amylose with acrylic acid. The structure of Am-g-PAA was confirmed by H-1 NMR and FT-IR spectra. The morphology, crystallinity and thermal properties of amylose and Am-g-PAA were investigated by SEM, XRD and TGA, respectively. The highest degree of substitution (DS) of carboxyl group was 1.96 which was obtained after reacted for 1 hat 60 degrees C. Acrylic acid to anhydroglucose mole ratio for DS was 19.81. It was found that a large number of carboxyl groups were grafted on the backbone of amylose. It was also found that ammonia adsorption capacity of amylose increased by grafting poly(acrylic acid) on the backbone of amylose. (C) 2016 Elsevier Ltd. All rights reserved.

引用

页码：429 / 434

页数：6

共 21 条

[1] Preparation of poly(acrylic acid)/starch hydrogel and its application for cadmium ion removal from aqueous solutions [J].