Electrochemical 3D printed copper garden for nitrate detection

被引:12
作者
Siddiqui, Hafsa [1 ]
Singh, Netrapal [1 ,2 ]
Chauhan, Viplov [3 ]
Sathish, N. [1 ,2 ]
Kumar, Surender [1 ,2 ]
机构
[1] CSIR Adv Mat & Proc Res Inst AMPRI, Bhopal 462026, India
[2] Acad Sci & Innovat Res Acsir, Ghaziabad 201002, India
[3] Inst Excellence Higher Educ IEHE, Bhopal 462016, India
关键词
Copper-garden; 3D printing; Nitrate detection; electrochemical additive manufacturing (ECAM); ELECTROCATALYTIC REDUCTION; ELECTRODES; METAL;
D O I
10.1016/j.matlet.2021.130795
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The present work deals with the electrochemical additive manufacturing (ECAM) process to fabricate stable copper electrode and their utilization in nitrate (NO3-) detection. The deposited copper on ITO through the ECAM process reveals the growth of crystalline Cu single-phase with FCC structure. The deposited copper electrode has a low electrical resistivity of -3.9x10- 5 omega cm at room temperature. Additionally, the printed copper electrode exhibits a good response range from 5 mu M - 2000 mu M (R2 = 0.998), with high sensitivity (2.61 mA/mu M- 1cm- 2), low detection limit -1.99 mu M, and impressive anti-interference ability towards detection of nitrate.
引用
收藏
页数:4
相关论文
共 16 条
[1]   Significance of nanomaterials in electrochemical sensors for nitrate detection: A review [J].
Amali, R. K. A. ;
Lim, H. N. ;
Ibrahim, I. ;
Huang, N. M. ;
Zainal, Z. ;
Ahmad, S. A. A. .
TRENDS IN ENVIRONMENTAL ANALYTICAL CHEMISTRY, 2021, 31
[2]   A Low Cost Desktop Electrochemical Metal 3D Printer [J].
Chen, Xiaolong ;
Liu, Xinhua ;
Childs, Peter ;
Brandon, Nigel ;
Wu, Billy .
ADVANCED MATERIALS TECHNOLOGIES, 2017, 2 (10)
[3]   Electrochemical detection of nitrate and nitrite at a copper modified electrode [J].
Davis, J ;
Moorcroft, MJ ;
Wilkins, SJ ;
Compton, RG ;
Cardosi, MF .
ANALYST, 2000, 125 (04) :737-741
[4]   Electrocatalytic reduction of nitrate at low concentration on coinage and transition-metal electrodes in acid solutions [J].
Dima, GE ;
de Vooys, ACA ;
Koper, MTM .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2003, 554 :15-23
[5]   Ion-Imprinted Electrochemical Sensor Based on Copper Nanoparticles-Polyaniline Matrix for Nitrate Detection [J].
Essousi, Houda ;
Barhoumi, Houcine ;
Bibani, Malek ;
Ktari, Nadia ;
Wendler, Frank ;
Al-Hamry, Ammar ;
Kanoun, Olfa .
JOURNAL OF SENSORS, 2019, 2019
[6]   Electrocatalytic reduction of nitrate: Fundamentals to full-scale water treatment applications [J].
Garcia-Segura, Sergi ;
Lanzarini-Lopes, Mariana ;
Hristovski, Kiril ;
Westerhoff, Paul .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2018, 236 :546-568
[7]   One metal is enough: a nickel complex reduces nitrate anions to nitrogen gas [J].
Gwak, Jinseong ;
Ahn, Seihwan ;
Baik, Mu-Hyun ;
Lee, Yunho .
CHEMICAL SCIENCE, 2019, 10 (18) :4767-4774
[8]   Copper nano-clusters prepared by one-step electrodeposition and its application on nitrate sensing [J].
Li, Y. ;
Sun, J. Z. ;
Bian, C. ;
Tong, J. H. ;
Dong, H. P. ;
Zhang, H. ;
Xia, S. H. .
AIP ADVANCES, 2015, 5 (04)
[9]   Micro electrochemical sensor with copper nanoclusters for nitrate determination in freshwaters [J].
Li, Yang ;
Sun, Jizhou ;
Bian, Chao ;
Tong, Jianhua ;
Xia, Shanhong .
MICRO & NANO LETTERS, 2012, 7 (12) :1197-1201
[10]   Nanowire-based Cu electrode as electrochemical sensor for detection of nitrate in water [J].
Liang, Jihong ;
Zheng, Yifan ;
Liu, Zongjian .
SENSORS AND ACTUATORS B-CHEMICAL, 2016, 232 :336-344