Solvent free oxidation of primary alcohols and diols using thymine iron(III) catalyst

被引：42

作者：

Al-Hunaiti, Afnan ^{[1
]}

Niemi, Teemu ^{[1
]}

Sibaouih, Ahlam ^{[1
]}

Pihko, Petri ^{[2
]}

Leskela, Markku ^{[1
]}

Repo, Timo ^{[1
]}

机构：

[1] Univ Helsinki, Dept Chem, Inorgan Chem Lab, FIN-00014 Helsinki, Finland

[2] Univ Jyvaskyla, Dept Chem, FI-40014 Jyvaskyla, Finland

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 48期

基金：

芬兰科学院;

关键词：

SELECTIVE AEROBIC OXIDATION; BENZYLIC ALCOHOLS; MOLECULAR-OXYGEN; PALLADIUM NANOPARTICLES; HYDROGEN-PEROXIDE; ALDEHYDES; EFFICIENT; KETONES; WATER; BENIGN;

D O I：

10.1039/c0cc04043f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this study, we developed an efficient and selective iron-based catalyst system for the synthesis of ketones from secondary alcohols and carboxylic acids from primary alcohol. In situ generated iron catalyst of thymine-1-acetate (THA) and FeCl3 under solvent-free condition exhibits high activity. As an example, 1-octanol and 2-octanol were oxidized to 1-octanoic acid and 2-octanone with 89% and 98% yields respectively.

引用

页码：9250 / 9252

页数：3

共 65 条

[61] Tojo G., 2006, OXIDATION PRIMARY AL
[62] Tojo G, 2006, BASIC REACT ORG SYNT, P1
[63] Catalytic oxidation of alcohols in water under atmospheric oxygen by use of an amphiphilic resin-dispersion of a nanopalladium catalyst
Uozumi, Y
Nakao, R
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (02) : 194 - +
[64] Recyclable carbon supported copper-manganese oxide for selective aerobic oxidation of alcohols in combination with 2,2,6,6-tetramethylpiperidyl-1-oxyl under neutral condition
Yang, Guanyu
Zhu, Weimin
Zhang, Panke
Xue, Huazhen
Wang, Wei
Tian, Junshan
Song, Maoping
[J]. ADVANCED SYNTHESIS & CATALYSIS, 2008, 350 (04) : 542 - 546
[65] A novel chromium trioxide catalyzed oxidation of primary alcohols to the carboxylic acids
Zhao, MZ
Li, J
Song, ZG
Desmond, R
Tschaen, DM
Grabowski, EJJ
Reider, PJ
[J]. TETRAHEDRON LETTERS, 1998, 39 (30) : 5323 - 5326

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