Solvent free oxidation of primary alcohols and diols using thymine iron(III) catalyst

被引：42
作者：
Al-Hunaiti, Afnan [1 ]
Niemi, Teemu [1 ]
Sibaouih, Ahlam [1 ]
Pihko, Petri [2 ]
Leskela, Markku [1 ]
Repo, Timo [1 ]
机构：
[1] Univ Helsinki, Dept Chem, Inorgan Chem Lab, FIN-00014 Helsinki, Finland
[2] Univ Jyvaskyla, Dept Chem, FI-40014 Jyvaskyla, Finland
来源：
CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 48期
基金：
芬兰科学院;
关键词：
SELECTIVE AEROBIC OXIDATION; BENZYLIC ALCOHOLS; MOLECULAR-OXYGEN; PALLADIUM NANOPARTICLES; HYDROGEN-PEROXIDE; ALDEHYDES; EFFICIENT; KETONES; WATER; BENIGN;
D O I：
10.1039/c0cc04043f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In this study, we developed an efficient and selective iron-based catalyst system for the synthesis of ketones from secondary alcohols and carboxylic acids from primary alcohol. In situ generated iron catalyst of thymine-1-acetate (THA) and FeCl3 under solvent-free condition exhibits high activity. As an example, 1-octanol and 2-octanol were oxidized to 1-octanoic acid and 2-octanone with 89% and 98% yields respectively.
引用
收藏
页码：9250 / 9252
页数：3
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