A novel perfluoroalkyl-containing bisulfite adduct of polyisocyanate: Synthesis and finishing of cotton fabrics

被引:6
作者
Jiang, WC
Meng, WD
Qing, FL [1 ]
机构
[1] Donghua Univ, Coll Chem & Chem Engn, Shanghai 200051, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Organofluorine Chem, Shanghai 200032, Peoples R China
关键词
D O I
10.1177/004051750507500309
中图分类号
TB3 [工程材料学]; TS1 [纺织工业、染整工业];
学科分类号
0805 ; 080502 ; 0821 ;
摘要
A perfluoroalkyl-containing diol (F-diol) is introduced into polyisocyanate, and novel bifunctional perfluoroalkyl-containing bisulfite adduct of polyisocyanate (FBAP) is successfully prepared after blocking with sodium metabisulfite. FBAP is applied to cotton fabrics by a pad-dry-cure process. The treated fabrics show good durable press and water and oil repellent properties: the dry wrinkle recovery angle reaches 210 degrees and the water and oil repellent ratings are 100 and 6, respectively. After. 10 washing cycles, the water repellent rating is still 90 and the oil repellent rating is 5.
引用
收藏
页码:240 / 244
页数:5
相关论文
共 15 条
[1]  
[Anonymous], 1998, MELLIAND INT, V4, P278
[2]   SOME APPROACHES TO THE SYNTHESIS OF FLUORINATED ALCOHOLS AND ESTERS .2. USE OF F-ALKYL IODIDES FOR THE SYNTHESIS OF F-ALKYL ALKANOLS [J].
BRACE, NO .
JOURNAL OF FLUORINE CHEMISTRY, 1982, 20 (03) :313-327
[3]   Chemistry of [(perfluoroalkyl)methyl] oxiranes. Regioselectivity of ring opening with O-nucleophiles and the preparation of amphiphilic monomers [J].
Cirkva, V ;
Ameduri, B ;
Boutevin, B ;
Paleta, O .
JOURNAL OF FLUORINE CHEMISTRY, 1997, 84 (01) :53-61
[4]   REACTION OF ISOCYANATES WITH BISULFITE SALTS [J].
GUISE, GB ;
JACKSON, MB ;
MACLAREN, JA .
AUSTRALIAN JOURNAL OF CHEMISTRY, 1972, 25 (12) :2583-&
[5]  
GUO CY, 1984, ACTA CHEM SINICA, V42
[6]   NEW DEVELOPMENTS IN THE CHEMICAL FINISHING OF TEXTILES [J].
HOLME, I .
JOURNAL OF THE TEXTILE INSTITUTE, 1993, 84 (04) :520-533
[7]  
Lu Y, 1999, TEXT RES J, V69, P685
[8]  
MORRELL BJ, 1992, TEXT RES J, V62, P144
[9]  
PERTSEN HA, 1983, CHEM PROCESSING FIBE, P47
[10]   Synthesis of perfluoroalkyl-containing multifunctional groups compounds for textile finishing [J].
Qing, FL ;
Ji, M ;
Lu, RH ;
Yan, KL ;
Mao, ZP .
JOURNAL OF FLUORINE CHEMISTRY, 2002, 113 (01) :139-141