Phase behavior of tetramethylurea plus MCl (M = Na, K, Rb, Cs) + H2O systems at 288.2, 298.2 and 308.2 K

被引：3

作者：

Cao, Xiaoyue ^{[1
]}

Chang, Yahui ^{[2
]}

Li, Shuni ^{[1
]}

Zhai, Quanguo ^{[1
]}

Jiang, Yucheng ^{[1
]}

Hu, Mancheng ^{[1
]}

机构：

[1] Shaanxi Normal Univ, Sch Chem & Chem Engn, Key Lab Macromol Sci Shaanxi Prov, Xian 710062, Shaanxi, Peoples R China

[2] Shaanxi Noma Univ, Sch Educ, Xian 710062, Shaanxi, Peoples R China

来源：

JOURNAL OF CHEMICAL THERMODYNAMICS | 2020年 / 144卷 / 144期

基金：

中国国家自然科学基金;

关键词：

MCl; (M; Na; K; Rb; Cs); Tetramethylurea; Phase equilibria; Density; Refractive index; AQUEOUS 2-PHASE SYSTEMS; LIQUID-LIQUID EQUILIBRIUM; WATER TERNARY-SYSTEMS; VOLUMETRIC PROPERTIES; REFRACTIVE-INDEX; VAPOR-PRESSURES; SODIUM-CHLORIDE; SOLUBILITY; TEMPERATURES; MIXTURES;

D O I：

10.1016/j.jct.2020.106058

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

For this article, we investigated the phase behavior and physicochemical properties of the ternary systems MCl (M = Na, K, Rb, Cs) + tetramethylurea (TMU) + H2O at temperatures of 288.2, 298.2 and 308.2 K. For (solid-liquid) equilibrium (SLE) systems (NaCl/KCl/RbCl + TMU + H2O at three temperatures and CsCl + TMU + H2O at 288.2 K), the density, solubility and refractive index about the saturated solutions was obtained. About (liquid-liquid) equilibrium (LLE) systems (CsCl + TMU + H2O at 298.2 and 308.2 K), the binodal curves and tie lines were obtained. The three parameter equation, Othmer-Tobias and Bancroft equations were used to correlate the SLE and LLE data. (C) 2020 Elsevier Ltd.

引用

页数：9

共 40 条

[1] The molar enthalpies of solution and vapour pressures of saturated aqueous solutions of some cesium salts [J].

Apelblat, A ;

Korin, E .

JOURNAL OF CHEMICAL THERMODYNAMICS, 2006, 38 (02) :152-157

[2] The vapour pressures of saturated aqueous solutions of sodium chloride, sodium bromide, sodium nitrate, sodium nitrite, potassium iodate, and rubidium chloride at temperatures from 227 K to 323 K [J].

Apelblat, A ;

Korin, E .

JOURNAL OF CHEMICAL THERMODYNAMICS, 1998, 30 (01) :59-71

[3] Volumetric properties of water, and solutions of sodium chloride and potassium chloride at temperatures from T=277.15 K to T=343.15 K at molalities of (0.1, 0.5, and 1.0) mol•kg-1 [J].

Apelblat, A ;

Manzurola, E .

JOURNAL OF CHEMICAL THERMODYNAMICS, 1999, 31 (07) :869-893

[4] Solubility of 1,3,5,7-tetra azatricyclo[3.3.1.13,7]decane (HMT) in water from 275.15 K to 313.15 K [J].

Blanco, L. H. ;

Sanabria, N. R. ;

Davila, M. T. .

THERMOCHIMICA ACTA, 2006, 450 (1-2) :73-75

[5] LIQUID-LIQUID EQUILIBRIUM OF AQUEOUS MIXTURES OF POLY(PROPYLENE GLYCOL) WITH NACL [J].

CHELUGET, EL ;

GELINAS, S ;

VERA, JH ;

WEBER, ME .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1994, 39 (01) :127-130

[6]

Francis T., 2017, Lean Transformations for Small and Medium Enterprises: Lessons Learned from Italian Businesses

[7] Measurement and Correlation of Solubilities and Solution Thermodynamics for N,N-Diethylformamide plus MCl (M = Na, K, Rb, and Cs) plus Water Systems in the Temperature Range 288.15-338.15 K [J].

Gao, Yunxue ;

Zhao, Dandan ;

Li, Shuni ;

Zhai, Quanguo ;

Jiang, Yucheng ;

Hu, Mancheng .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2016, 61 (04) :1649-1656

[8] Volumetric properties of binary mixtures of (N, N-diethylformamide plus xylenes) at temperatures between T=293.15 K and T-=53.15 K at p=0.1 MPa [J].

Gu, Yongqing ;

Wu, Jiang .

JOURNAL OF MOLECULAR LIQUIDS, 2008, 137 (1-3) :165-173

[9] Equilibrium Phase Behavior of Aqueous Two-Phase Systems Containing 1-Alkyl-3-methylimidazolium Tetrafluoroborate and Ammonium Tartrate at Different Temperatures: Experimental Determination and Correlation [J].

Han, Juan ;

Wang, Yun ;

Li, Yanfang ;

Yu, Cuilan ;

Yan, Yongsheng .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2011, 56 (09) :3679-3687

[10] Solubility of Sodium Halides in Aqueous Mixtures with ε-Increasing Cosolvents: Formamide, N-Methylformamide, and N-Methylacetamide at 298.15 K [J].

Hernandez-Luis, Felipe ;

Rodriguez-Raposo, Raquel ;

Galleguillos, Hector R. ;

Morales, Jaime W. .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2016, 55 (03) :812-819

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