Catalytic hydrogenation of CO2 with unsymmetric N-heterocyclic carbene-nitrogen-phosphine ruthenium complexes

被引：7
|
作者：
Ji, Li [1 ]
Cui, Tianhua [1 ]
Nie, Xufeng [1 ]
Zheng, Yanling [1 ]
Zheng, Xueli [1 ]
Fu, Haiyan [1 ]
Yuan, Maolin [1 ]
Chen, Hua [1 ]
Xu, Jiaqi [1 ]
Li, Ruixiang [1 ]
机构：
[1] Sichuan Univ, Coll Chem, Minist Educ, Key Lab Green Chem & Technol, Chengdu 610064, Sichuan, Peoples R China
来源：
CATALYSIS SCIENCE & TECHNOLOGY | 2021年 / 11卷 / 21期
基金：
中国博士后科学基金; 中国国家自然科学基金;
关键词：
CARBON-DIOXIDE HYDROGENATION; FORMIC-ACID DEHYDROGENATION; HOMOGENEOUS HYDROGENATION; PINCER LIGANDS; FORMATE; IRIDIUM; AMINES;
D O I：
10.1039/d1cy01713f
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Unsymmetric Ru-CNP and Ru-CN(H)P complexes are synthesized and applied in the hydrogenation of CO2 to formate for the first time. The Ru-CNP complex shows excellent stability and high activity. The TON is around 170 000 after 48 h at 200 degrees C, which is a relatively high record value among all the Ru complexes.
引用
收藏
页码：6965 / 6969
页数：5
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