Decoupling of exchange and persistence times in atomistic models of glass formers

被引:84
作者
Hedges, Lester O.
Maibaum, Lutz
Chandler, David
Garrahan, Juan P. [1 ]
机构
[1] Univ Nottingham, Sch Phys & Astron, Nottingham NG7 2RD, England
[2] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
基金
美国国家科学基金会; 英国工程与自然科学研究理事会;
关键词
SPATIALLY HETEROGENEOUS DYNAMICS; DENSITY CORRELATION-FUNCTION; SUPERCOOLED LIQUIDS; MOLECULAR-DYNAMICS; TRANSITION; RELAXATION; DIFFUSION; MIXTURE; SPACE;
D O I
10.1063/1.2803062
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
With molecular dynamics simulations of a fluid mixture of classical particles interacting with pairwise additive Weeks-Chandler-Andersen potentials, we consider the time series of particle displacements and thereby determine the distributions for local persistence times and local exchange times. These basic characterizations of glassy dynamics are studied over a range of supercooled conditions and were shown to have behaviors, most notably decoupling, similar to those found in kinetically constrained lattice models of structural glasses. Implications are noted.
引用
收藏
页数:4
相关论文
共 39 条
[1]   Dynamic entropy as a measure of caging and persistent particle motion in supercooled liquids [J].
Allegrini, P ;
Douglas, JF ;
Glotzer, SC .
PHYSICAL REVIEW E, 1999, 60 (05) :5714-5724
[2]   Molecular dynamics studies of heterogeneous dynamics and dynamic crossover in supercooled atomic liquids [J].
Andersen, HC .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2005, 102 (19) :6686-6691
[3]   Time and length scales in supercooled liquids [J].
Berthier, L .
PHYSICAL REVIEW E, 2004, 69 (02) :020201-1
[4]   Spontaneous and induced dynamic correlations in glass formers. II. Model calculations and comparison to numerical simulations [J].
Berthier, L. ;
Biroli, G. ;
Bouchaud, J.-P. ;
Kob, W. ;
Miyazaki, K. ;
Reichman, D. R. .
JOURNAL OF CHEMICAL PHYSICS, 2007, 126 (18)
[5]   The Monte Carlo dynamics of a binary Lennard-Jones glass-forming mixture [J].
Berthier, L. ;
Kob, W. .
JOURNAL OF PHYSICS-CONDENSED MATTER, 2007, 19 (20)
[6]   Length scale for the onset of Fickian diffusion in supercooled liquids [J].
Berthier, L ;
Chandler, D ;
Garrahan, JP .
EUROPHYSICS LETTERS, 2005, 69 (03) :320-326
[7]   Three-dimensional imaging of colloidal glasses under steady shear [J].
Besseling, R. ;
Weeks, Eric R. ;
Schofield, A. B. ;
Poon, W. C. K. .
PHYSICAL REVIEW LETTERS, 2007, 99 (02)
[8]   Lengthscale dependence of dynamic four-point susceptibilities in glass formers [J].
Chandler, David ;
Garrahan, Juan P. ;
Jack, Robert L. ;
Maibaum, Lutz ;
Pan, Albert C. .
PHYSICAL REVIEW E, 2006, 74 (05)
[9]   Heterogeneity at the glass transition: Translational and rotational self-diffusion [J].
Chang, I ;
Sillescu, H .
JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (43) :8794-8801
[10]   Universal nature of particle displacements close to glass and jamming transitions [J].
Chaudhuri, Pinaki ;
Berthier, Ludovic ;
Kob, Walter .
PHYSICAL REVIEW LETTERS, 2007, 99 (06)