Densities, excess molar volumes, viscosities, speeds of sound, excess isentropic compressibilities, and relative permittivities for alkyl (methyl, ethyl, butyl, and isoamyl) acetates plus glycols at different temperatures

被引:122
作者
Sastry, NV [1 ]
Patel, MC [1 ]
机构
[1] Sardar Patel Univ, Dept Chem, Vallabh Vidyanagar 388120, Gujarat, India
关键词
D O I
10.1021/je0340248
中图分类号
O414.1 [热力学];
学科分类号
摘要
New experimental data on densities at (298.15 to 313.15) K, viscosities, speeds of sound, and relative permittivities at (298.15 and 308.15) K for the 10 binary mixtures of alkyl (methyl, ethyl, butyl, and isoamyl) acetates + glycols (ethylene, diethylene, triethylene, and propylene) have been measured as a function of the composition. Deviation functions, such as deviations in speeds of sound and deviations in relative permittivities, and excess functions, such as excess molar volumes and excess isentropic compressibilities, were calculated and fitted to a Redlich-Kister type equation. Grunberg-Nissan, McAllister, and Auslander equations correlated the mixture viscosities adequately. The values of speeds of sound in these mixtures, as predicted by collision factor theory, matched well with experimental data. The variation of the Kirkwood correlation factor with the ester mole fraction was examined. A qualitative analysis of the deviation and excess functions was made to ascertain the nature and type of bulk state interactions.
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页码:1019 / 1027
页数:9
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