Shaping metal-organic framework (MOF) powder materials for CO2 capture applications-a thermogravimetric study

被引：26

作者：

Majchrzak-Kuceba, Izabela ^{[1
]}

Sciubidlo, Aleksandra ^{[1
]}

机构：

[1] Czestochowa Tech Univ, Inst Adv Energy Technol, Fac Infrastruct & Environm, Dabrowskiego St 73, PL-42201 Czestochowa, Poland

来源：

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 2019年 / 138卷 / 06期

关键词：

CO2; capture; MOFS; Thermogravimetric study; TG-Vacuum; CARBON-DIOXIDE; PELLETIZATION PRESSURE; SEPARATION; ADSORPTION;

D O I：

10.1007/s10973-019-08314-5

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The paper presents the effect of the tabletting pressure and time on the chemical structure and crystallinity of the CuBTC and MIL-53(Al) metal-organic framework tablets. For MOFs, the no-binder tabletting method was employed using a pressure of 3.7, 7.4, 29.6 and 59.2 kN m(-2), respectively, for a duration of 0.5, 1 and 2 min. The obtained tablets were crushed and sieved to obtain the desired fraction from 500 to 650 mu m. In this study, the thermogravimetric test has been used for the assessment of the effect of shaping metal-organic frameworks on the CO2 adsorption properties. The examination of the CO2 sorption capacity of metal-organic frameworks was carried out using a Mettler TGA/SDTA 851e thermobalance and TG-Vacuum. The results indicate a significant effect of compression on the crystal structure and CO2 sorption capacity of MOFs.

引用

收藏

页码：4139 / 4144

页数：6

相关论文

共 20 条

[11] A rationale for the large breathing of the porous aluminum terephthalate (MIL-53) upon hydration [J].

Loiseau, T ;

Serre, C ;

Huguenard, C ;

Fink, G ;

Taulelle, F ;

Henry, M ;

Bataille, T ;

Férey, G .

CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (06) :1373-1382

[12] Regeneration performance of metal-organic frameworks TG-Vacuum tests [J].

Majchrzak-Kuceba, Izabela ;

Bukalak-Gaik, Dominika .

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2016, 125 (03) :1461-1466

[13] Effects of pelletization pressure on the physical and chemical properties of the metal-organic frameworks Cu3(BTC)2 and UiO-66 [J].

Peterson, Gregory W. ;

DeCoste, Jared B. ;

Glover, T. Grant ;

Huang, Yougui ;

Jasuja, Himanshu ;

Walton, Krista S. .

MICROPOROUS AND MESOPOROUS MATERIALS, 2013, 179 :48-53

[14] Removal of the CO2 from flue gas utilizing hybrid composite adsorbent MIL-53(Al)/GNP metal-organic framework [J].

Pourebrahimi, Sina ;

Kazemeini, Mohammad ;

Babakhani, Ensieh Ganji ;

Taheri, Armin .

MICROPOROUS AND MESOPOROUS MATERIALS, 2015, 218 :144-152

[15] Shaping amine-based solid CO2 adsorbents: Effects of pelletization pressure on the physical and chemical properties [J].

Rezaei, Fateme ;

Sakwa-Novak, Miles A. ;

Bali, Sumit ;

Duncanson, Daniel M. ;

Jones, Christopher W. .

MICROPOROUS AND MESOPOROUS MATERIALS, 2015, 204 :34-42

[16] Carbon dioxide capturing technologies: a review focusing on metal organic framework materials (MOFs) [J].

Sabouni, Rana ;

Kazemian, Hossein ;

Rohani, Sohrab .

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH, 2014, 21 (08) :5427-5449

[17] Adsorption microcalorimetry of small molecules on various metal-organic frameworks [J].

Saha, Arindom ;

Strickland, Danny .

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2016, 126 (03) :1747-1755

[18] Shape engineering of metal-organic frameworks [J].

Valizadeh, Bardiya ;

Nguyen, Tu N. ;

Stylianou, Kyriakos C. .

POLYHEDRON, 2018, 145 :1-15

[19] Thermodynamic properties of 3D copper(II)-MOFs assembled by 1H-tetrazole [J].

Yang, Qi ;

Yang, Guoli ;

Ge, Jing ;

Yang, Langlei ;

Song, Xiaxia ;

Wei, Qing ;

Xie, Gang ;

Chen, Sanping ;

Gao, Shengli .

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2017, 128 (02) :1175-1182

[20] Shaping of ultrahigh-loading MOF pellet with a strongly anti-tearing binder for gas separation and storage [J].

Zheng, Jieyi ;

Cui, Xili ;

Yang, Qiwei ;

Ren, Qilong ;

Yang, Yiwen ;

Xing, Huabin .

CHEMICAL ENGINEERING JOURNAL, 2018, 354 :1075-1082