Utilizing human hair for solid-state flexible fiber-based asymmetric supercapacitors

被引:27
作者
Zhao, Jing [1 ]
Gong, Junwei [1 ]
Zhou, Chunliang [1 ]
Miao, Chenxu [1 ]
Hu, Rong [1 ]
Zhu, Kai [1 ]
Cheng, Kui [1 ]
Ye, Ke [1 ]
Yan, Jun [1 ]
Cao, Dianxue [1 ]
Zhang, Xianfa [2 ]
Wang, Guiling [1 ]
机构
[1] Harbin Engn Univ, Dept Mat Sci & Engn, Key Lab Superlight Mat & Surface Technol, Minist Educ, Harbin 150001, Heilongjiang, Peoples R China
[2] Heilongjiang Univ, Sch Chem & Mat Sci, Key Lab Funct Inorgan Mat Chem, Harbin 150080, Peoples R China
基金
中国国家自然科学基金; 中央高校基本科研业务费专项资金资助;
关键词
Human hair fibers; Reduced graphene oxide; Microwave-assisted method; Flexible fiber-based supercapacitor; METAL-ORGANIC FRAMEWORK; ONE-STEP SYNTHESIS; GRAPHENE OXIDE; CARBON NANOSHEETS; POROUS CARBON; BIOMASS; REDUCTION; TEMPLATE; NANOTUBE; FABRICATION;
D O I
10.1016/j.apsusc.2020.145260
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The demands for wearable energy storage devices keep growing and novel flexible electrode materials and facile prepared methods for these devices are crucial and attractive. In this work, human hair fiber is employed as the flexible fiber-based material due to the high utilization values of low cost, controllable length and high elasticity capable. Herein, an effective and hazard-free microwave-assisted method is reported to develop superelastic reduced graphene oxide coating human hair (rGO@Hh) to achieve conductive and high-strength fibrous electrode. With the braided rGO@Hh fibers, nickel hydroxide nanoribbon-intercalated rGO nanosheets (Ni(OH)(2)/rGO@Hh) are further prepared through microwave radiation treatment, which shows an interconnected porous structure with outstanding electrochemical performances of high specific capacitance (316 F g(-1) at 1 A g(-1)) and good cycling performance. Moreover, a solid-state fiber-based asymmetric supercapacitor (FASC) is assembled with rGO@Hh fibers and Ni(OH)(2)/rGO@Hh fibers as negative and positive electrodes, which demonstrates a high energy of 27.6 Wh kg(-1) and a power density of 699 W kg(-1), respectively. The FASC also can be further used for numerous electronic products, presenting its prospect for portable wearable devices with high tensile strength and excellent performances.
引用
收藏
页数:9
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