Copper-catalyzed highly enantioselective synthesis of cyclic allylic and homoallylic alcohols with dialkylzinc reagents

被引：0
作者：
Pineschi, M [1 ]
Del Moro, F [1 ]
Crotti, P [1 ]
Di Bussolo, V [1 ]
Macchia, F [1 ]
机构：
[1] Univ Pisa, Dipartimento Chim Bioorgan & Biofarm, I-56126 Pisa, Italy
来源：
SYNTHESIS-STUTTGART | 2005年 / 02期
关键词：
asymmetric catalysis; organozinc reagents; copper; kinetic resolution; desymmetrization;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The copper-phosphoramidite catalyzed addition of dialkylzinc reagents to racemic or meso allylic epoxides can be synthetically exploited in different ways, depending on the substrates and reaction conditions used.
引用
收藏
页码：334 / 337
页数：4
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