Heteroleptic phthalocyaninato-[2,3,9,10,16,17,23,24-octakis(octyloxy)phthalocyaninato] rare earth(III) triple-deckers: synthesis and spectroscopic characterization

被引：49

作者：

Liu, W

Jiang, JZ ^{[1
]}

Pan, N

Arnold, DP

机构：

[1] Shandong Univ, Dept Chem, Kay Lab Colloid & Interface Chem Statr Educ Minis, Jinan 250100, Peoples R China

[2] QUT, CIDC, Sch Phys Sci, Brisbane, Qld 4001, Australia

来源：

INORGANICA CHIMICA ACTA | 2000年 / 310卷 / 02期

基金：

中国国家自然科学基金; 澳大利亚研究理事会;

关键词：

phthalocyaninato complexes; rare earth complexes; triple-decker sandwiches;

D O I：

10.1016/S0020-1693(00)00258-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The homo-dinuclear heteroleptic phthalocyaninato-[2,3,9,10,16,17,23,24-octakis(octyloxy)phthalocyaninato] rare earth(III) triple-decker complexes (Pc)M[Pc(OC8H17)(8)]M[Pc(OC8H17)(8)] (M = Pr, Nd, Sm, Eu, Tb, Dy, Y, Ho, Er, Tm) (1a-10a) and (Pc)M[Pc(OC8H17)(8)]M(Pc) (M = Nd, Sm, Eu, Tb, Dy, Y, Ho, Er, Tm) (2b-10b) were obtained by condensation of bis(phthalocyaninato) rare earths M[Pc(OC8H17)(8)](2) (M = Pr, Nd, Sm, Eu, Tb, Dy, Y, Ho, Er, Tm), Li-2(Pc) and M(acac)(3). nH(2)O (M = Pr, Nd, Sm. Eu, Tb, Dy, Y, Ho, Er, Tm). These novel compounds were characterized by H-1 NMR, mass, electronic absorption (UV-Vis). and IR spectroscopic methods. (C) 2000 Elsevier Science B.V. All rights reserved.

引用

页码：140 / 146

页数：7

共 37 条

[11] BIS(2,3-NAPHTHALOCYANINATO)LUTETIUM(III) AND (2,3-NAPHTHALOCYANINATO)(PHTHALOCYANINATO)LUTETIUM(III) COMPLEXES - SYNTHESIS, SPECTROSCOPIC CHARACTERIZATION, AND ELECTROCHEMISTRY [J].