A mild and efficient procedure for the oxidation of epoxides and aziridines using cerium(IV) ammonium nitrate and NBS

被引：40
|
作者：
Surendra, K [1 ]
Krishnaveni, NS [1 ]
Rao, KR [1 ]
机构：
[1] Indian Inst Chem Technol, Organ Chem Div 1, Hyderabad 500007, Andhra Pradesh, India
来源：
TETRAHEDRON LETTERS | 2005年 / 46卷 / 23期
关键词：
oxiranes; aziridines; alpha-hydroxy ketones; alpha-amino ketones; CAN; NBS; oxidation;
D O I：
10.1016/j.tetlet.2005.04.008
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The CAN and NBS combination has been used for the first time for the synthesis of versatile alpha-hydroxy ketones and alpha-amino ketones from oxiranes/aziridines, respectively, in excellent yields. This method is a direct, one-pot, synthesis under mild conditions using acetonitrile-water (9:1) as solvent. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码：4111 / 4113
页数：3
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