A mild and efficient procedure for the oxidation of epoxides and aziridines using cerium(IV) ammonium nitrate and NBS

被引：41

作者：

Surendra, K ^{[1
]}

Krishnaveni, NS ^{[1
]}

Rao, KR ^{[1
]}

机构：

[1] Indian Inst Chem Technol, Organ Chem Div 1, Hyderabad 500007, Andhra Pradesh, India

来源：

TETRAHEDRON LETTERS | 2005年 / 46卷 / 23期

关键词：

oxiranes; aziridines; alpha-hydroxy ketones; alpha-amino ketones; CAN; NBS; oxidation;

D O I：

10.1016/j.tetlet.2005.04.008

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The CAN and NBS combination has been used for the first time for the synthesis of versatile alpha-hydroxy ketones and alpha-amino ketones from oxiranes/aziridines, respectively, in excellent yields. This method is a direct, one-pot, synthesis under mild conditions using acetonitrile-water (9:1) as solvent. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：4111 / 4113

页数：3

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