KINETICS OF OXIDATION OF GLYCINE BY ALKALINE HEXACYANOFERRATE(III)

被引：0

作者：

Laloo, D. ^{[1
]}

Mahanti, M. K. ^{[1
,2
]}

机构：

[1] NE Hill Univ, Dept Chem, Shillong 793022, Meghalaya, India

[2] Natl Inst Sci Educ & Res, Bhubaneswar 751005, Orissa, India

来源：

OXIDATION COMMUNICATIONS | 2010年 / 33卷 / 03期

关键词：

kinetics; oxidation; glycine; alkaline hexacyanoferrate(III); ALPHA-AMINO-ACIDS; ALIPHATIC AMINES; MECHANISM;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction between glycine and potassium hexacyanoferrate(III), in alkaline medium, at constant ionic strength, gave glyoxylic acid. The rate of the reaction was dependent on the first powers of the concentrations of substrate and oxidant, but was independent of the concentration of alkali in the range studied. The slow step of the reaction involved the formation of a radical intermediate, which was detected by ESR spectroscopy as a 7-line spectrum with peak intensity ratios of 1:5:11:14:11:5:1.

引用

页码：529 / 533

页数：5

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