An Aqueous Rechargeable Zn//Co3O4 Battery with High Energy Density and Good Cycling Behavior

被引:492
作者
Wang, Xiaowei [1 ,2 ,3 ,4 ]
Wang, Faxing [1 ,2 ]
Wang, Liying [1 ,2 ,5 ]
Li, Minxia [3 ,4 ]
Wang, Yanfang [3 ,4 ]
Chen, Bingwei [3 ,4 ]
Zhu, Yusong [1 ,2 ]
Fu, Lijun [1 ,2 ]
Zha, Liusheng [5 ]
Zhang, Lixin [3 ,4 ]
Wu, Yuping [1 ,2 ,3 ,4 ]
Huang, Wei [1 ,2 ]
机构
[1] Nanjing Tech Univ, Coll Energy, Nanjing 211816, Jiangsu, Peoples R China
[2] Nanjing Tech Univ, Inst Adv Mat, Nanjing 211816, Jiangsu, Peoples R China
[3] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China
[4] Fudan Univ, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China
[5] Donghua Univ, State Key Lab Modificat Chem Fibres & Polymer Mat, Shanghai 201620, Peoples R China
基金
中国国家自然科学基金;
关键词
LAYERED DOUBLE HYDROXIDE; ZN SECONDARY BATTERIES; HIGH-PERFORMANCE; ALKALINE BATTERIES; THIN-FILMS; ELECTROCHEMICAL PERFORMANCE; ASYMMETRIC SUPERCAPACITORS; ANODE MATERIAL; NI FOAM; ZINC;
D O I
10.1002/adma.201505370
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An aqueous rechargeable Zn//Co3O4 battery is demonstrated with Zn@carbon fibers and Co3O4@Ni foam as the negative and positive electrodes, respectively, using an electrolyte of 1 M KOH and 10 x 10(-3) M Zn(Ac)(2). It can operate at a cell voltage as high as 1.78 V with an energy density of 241 W h kg(-1) and presents excellent cycling. The battery is also assembled into a flexible shape, which can be applied in flexible or wearable devices requiring high energy.
引用
收藏
页码:4904 / 4911
页数:8
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