Simultaneous removal of Sb(III) and Cd(II) in water by adsorption onto a MnFe2O4 biochar nanocomposite

被引:102
|
作者
Wang, Yu-Ying [1 ,2 ]
Ji, Hai-Yang [1 ,3 ]
Lu, Hao-Hao [1 ,2 ]
Liu, Yu-Xue [1 ,2 ]
Yang, Rui-Qin [4 ,5 ]
He, Li-Li [1 ,2 ]
Yang, Sheng-Mao [1 ,2 ,3 ]
机构
[1] Zhejiang Acad Agr Sci, Inst Environm Resource Soil & Fertilizer, Hangzhou 310021, Zhejiang, Peoples R China
[2] Engn Res Ctr Biochar Zhejiang Prov, Hangzhou 310021, Zhejiang, Peoples R China
[3] Zhejiang Normal Univ, Coll Chem & Life Sci, Jinhua 321004, Peoples R China
[4] Zhejiang Univ Sci & Technol, Zhejiang Prov Collaborat Innovat Ctr Agr Biol Res, Hangzhou 310023, Zhejiang, Peoples R China
[5] Zhejiang Univ Sci & Technol, Zhejiang Prov Key Lab Chem & Bio Proc Technol Far, Hangzhou 310023, Zhejiang, Peoples R China
来源
RSC ADVANCES | 2018年 / 8卷 / 06期
关键词
AQUEOUS-SOLUTION; COMPETITIVE ADSORPTION; IN-SITU; ANTIMONY III; METAL IONS; ADSORBENT; PYROLYSIS; MECHANISM; PHOSPHATE; AMMONIUM;
D O I
10.1039/c7ra13151h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this study, a jacobsite-biochar nanocomposite (MnFe2O4-BC) was fabricated and used to simultaneously remove Sb(III) and Cd(II) from water via adsorption. The MnFe2O4-BC nanocomposite was prepared via a co-precipitation method and analyzed using various techniques. The results confirm the successful decoration of the biochar surface with MnFe2O4 nanoparticles. The maximum Sb(III) removal efficiency was found to be higher from bi-solute solutions containing Cd(II) than from single-solute systems, suggesting that the presence of Cd(II) enhances the removal of Sb(III). The Langmuir isotherm model describes well Sb(III) and Cd(II) removal via adsorption onto the MnFe2O4-BC nanocomposite. The maximum adsorption capacities are 237.53 and 181.49 mg g(-1) for Sb(III) and Cd(II), respectively, in a bisolute system. Thus, the prepared MnFe2O4-BC nanocomposite is demonstrated to be a potential adsorbent for simultaneously removing Sb(III) and Cd(II) ions from aqueous solutions.
引用
收藏
页码:3264 / 3273
页数:10
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