Preparation of green sodium alginate adsorption membrane and its high adsorption performance for fluoroquinolones antibiotics br

被引：13
作者：
Liu, Feng [1 ]
Zhou, Zhiyong [1 ]
Tu, Yuming [1 ]
Chen, Jianjie [1 ]
Zhang, Fan [1 ]
Tian, Shichao [1 ,2 ]
Ren, Zhongqi [1 ,2 ]
机构：
[1] Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China
[2] 15, N 3rd Ring Rd East, Beijing 100029, Peoples R China
来源：
JOURNAL OF WATER PROCESS ENGINEERING | 2022年 / 49卷
基金：
中国国家自然科学基金;
关键词：
Fluoroquinolones; Sodium alginate; Adsorption membrane; Adsorption performance; Crosslinking; AQUEOUS-SOLUTIONS; WASTE-WATER; CIPROFLOXACIN; REMOVAL; LEVOFLOXACIN; CARBON; MECHANISMS; CHITOSAN; SLUDGE; BEADS;
D O I：
10.1016/j.jwpe.2022.103124
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
Fluoroquinolones (FQs) were widely used in human and veterinary medicine, however, the presence of FQs at lower concentration in the environment could threaten to human health and agricultural production. In this research, the adsorption membranes were prepared based on sodium alginate (SA) crosslinking with multivalent metal ions. The SA-Al/Ca membranes and SA-Ca membrane were prepared by crosslinking with AlCl3/CaCl2 solutions and CaCl2 solutions, respectively. Comparing with SA-Ca membrane, the presence of Al3+in cross-linking agent could produce a large number of adsorption sites on the surface of SA-Al/Ca membrane and remarkably improve the adsorption performance of SA-Al/Ca membrane. Effects of preparation conditions such as crosslinking ways, CaCl2 percentage in compound crosslinker, and crosslinking time on the adsorption per-formance of prepared SA-Al/Ca membrane were demonstrated. Moreover, the effects of the initial concentration of ciprofloxacin (CIP) and Levofloxacin (S-OFX), adsorption time, solution pH, ionic strength and adsorption temperature on the performance of SA-Al/Ca membrane were studied. The thermodynamics of the adsorption of CIP and S-OFX were well fitted with the Tempkin adsorption isotherm model (R2 =0.9455) and D-R adsorption isotherm model (R2 =0.9822), respectively. The maximum adsorption capacity of S-OFX and CIP using SA-Al/Ca membrane was 836.31 mg.g1 and 858.94 mg.g1. The results showed that SA-Al/Ca membranes with good adsorption capacity, low cost and high stability
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页数：11
相关论文
共 48 条
[11]   Changing aetiology, clinical features, antimicrobial resistance, and outcomes of bloodstream infection in neutropenic cancer patients [J].
Gudiol, C. ;
Bodro, M. ;
Simonetti, A. ;
Tubau, F. ;
Gonzalez-Barca, E. ;
Cisnal, M. ;
Domingo-Domenech, E. ;
Jimenez, L. ;
Carratala, J. .
CLINICAL MICROBIOLOGY AND INFECTION, 2013, 19 (05) :474-479
[12]   Novel synthesis of natural cation exchange resin by crosslinking the sodium alginate as a natural polymer with 1,6-hexamethylene diisocyanate in inert solvents: Characteristics and applications [J].
Hassan , Refat M. .
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2021, 184 :926-935
[13]   Removal of ciprofloxacin from water by birnessite [J].
Jiang, Wei-Teh ;
Chang, Po-Hsiang ;
Wang, Ya-Siang ;
Tsai, Yolin ;
Jean, Jiin-Shuh ;
Li, Zhaohui ;
Krukowski, Keith .
JOURNAL OF HAZARDOUS MATERIALS, 2013, 250 :362-369
[14]   Alginate/gelatin mineralized hydrogel modified by multilayers electrospun membrane of cellulose: Preparation, properties and in-vitro degradation [J].
Jing, Yidan ;
Mahmud, Sakil ;
Wu, Chenfeng ;
Zhang, Xiaomin ;
Su, Shengpei ;
Zhu, Jin .
POLYMER DEGRADATION AND STABILITY, 2021, 192
[15]   Novel poly(vinyl alcohol) nanofiltration membrane modified with dopamine coated anatase TiO2 core shell nanoparticles [J].
Khalid, Faiz ;
Tabish, M. ;
Bora, Kainat Amin Ismail .
JOURNAL OF WATER PROCESS ENGINEERING, 2020, 37
[16]   Antibiotics in the aquatic environment - A review - Part II [J].
Kuemmerer, Klaus .
CHEMOSPHERE, 2009, 75 (04) :435-441
[17]   Effluent from drug manufactures contains extremely high levels of pharmaceuticals [J].
Larsson, D. G. Joakim ;
de Pedro, Cecilia ;
Paxeus, Nicklas .
JOURNAL OF HAZARDOUS MATERIALS, 2007, 148 (03) :751-755
[18]   Biodegradation and Adsorption of Antibiotics in the Activated Sludge Process [J].
Li, Bing ;
Zhang, Tong .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2010, 44 (09) :3468-3473
[19]   Filtration and adsorption properties of porous calcium alginate membrane for methylene blue removal from water [J].
Li, Qi ;
Li, Yanhui ;
Ma, Xiaomei ;
Du, Qiuju ;
Sui, Kunyan ;
Wang, Dechang ;
Wang, Cuiping ;
Li, Hongliang ;
Xia, Yanzhi .
CHEMICAL ENGINEERING JOURNAL, 2017, 316 :623-630
[20]   Novel magnetic beads based on sodium alginate gel crosslinked by zirconium(IV) and their effective removal for Pb2+ in aqueous solutions by using a batch and continuous systems [J].
Li, Xiaoli ;
Qi, Yongxin ;
Li, Yanfeng ;
Zhang, Yun ;
He, Xinghua ;
Wang, Yonghuan .
BIORESOURCE TECHNOLOGY, 2013, 142 :611-619
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