Comment on "Merging of α and slow β relaxation in supercooled liquids" -: art. no. 043501

被引:18
作者
Bergman, R [1 ]
Svanberg, C [1 ]
机构
[1] Chalmers Univ Technol, Dept Appl Phys, SE-41296 Gothenburg, Sweden
来源
PHYSICAL REVIEW E | 2005年 / 72卷 / 04期
关键词
D O I
10.1103/PhysRevE.72.043501
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
Fujima [T. Fujima, H. Frusawa, and K. Ito, Phys. Rev. E 66, 031503 (2002)] report on broadband dielectric relaxation measurements on two glass-formers. They find that the relaxation times of the beta relaxation follow different temperature dependences above and below the glass-transition temperature, T-g; i.e., there appears to be a crossover at T-g where the activation energy of the beta relaxation change. In this Comment we show that the observed behavior can be explained by analyzing the merging of the alpha and beta relaxations using an approach proposed by Williams. This analysis clearly shows that the low temperature (below T-g) behaviors of the alpha and beta relaxations can be used to describe also the high-temperature behavior (above T-g). The apparent change in activation energy is thus not to be identified with a change in relaxation mechanism.
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